N-(4-Bromophenyl)urea
In the title compound, C7H7BrN2O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedra...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810041735 |
| _version_ | 1819278052504371200 |
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| author | Petr Štěpnička Ivana Císařová |
| author_facet | Petr Štěpnička Ivana Císařová |
| author_sort | Petr Štěpnička |
| collection | DOAJ |
| description | In the title compound, C7H7BrN2O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedral angle of 47.8 (1)°. The crystal assembly is stabilized by N—H...O hydrogen bonds between all NH protons as conventional hydrogen bond donors and the C=O oxygen as a trifurcated hydrogen-bond acceptor. Both the overall molecular geometry and the crystal packing of the title compound are very similar to those of N-phenylurea, which is underscored by a practically isostructural relationship between these two urea derivatives. |
| first_indexed | 2024-12-24T00:05:53Z |
| format | Article |
| id | doaj.art-a2ee1a1d924942538b531abac74916a4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:05:53Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a2ee1a1d924942538b531abac74916a42022-12-21T17:25:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611o2879o287910.1107/S1600536810041735N-(4-Bromophenyl)ureaPetr ŠtěpničkaIvana CísařováIn the title compound, C7H7BrN2O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedral angle of 47.8 (1)°. The crystal assembly is stabilized by N—H...O hydrogen bonds between all NH protons as conventional hydrogen bond donors and the C=O oxygen as a trifurcated hydrogen-bond acceptor. Both the overall molecular geometry and the crystal packing of the title compound are very similar to those of N-phenylurea, which is underscored by a practically isostructural relationship between these two urea derivatives.http://scripts.iucr.org/cgi-bin/paper?S1600536810041735 |
| spellingShingle | Petr Štěpnička Ivana Císařová N-(4-Bromophenyl)urea Acta Crystallographica Section E |
| title | N-(4-Bromophenyl)urea |
| title_full | N-(4-Bromophenyl)urea |
| title_fullStr | N-(4-Bromophenyl)urea |
| title_full_unstemmed | N-(4-Bromophenyl)urea |
| title_short | N-(4-Bromophenyl)urea |
| title_sort | n 4 bromophenyl urea |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810041735 |
| work_keys_str_mv | AT petramp352tamp283pniamp269ka n4bromophenylurea AT ivanacamp237saamp345ovamp225 n4bromophenylurea |