Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate
In the title compound, [Zn(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate ligand, a bidentate ancillary 1,10-phenanthroline (phen) ligand and a water molecule complete a distorted octahedral coordination geometry around the ZnII atom. The pterin ligand fo...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-09-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015014619 |
| _version_ | 1798031427422388224 |
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| author | Siddhartha S. Baisya Baidyanath Ghosh Parag S. Roy |
| author_facet | Siddhartha S. Baisya Baidyanath Ghosh Parag S. Roy |
| author_sort | Siddhartha S. Baisya |
| collection | DOAJ |
| description | In the title compound, [Zn(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate ligand, a bidentate ancillary 1,10-phenanthroline (phen) ligand and a water molecule complete a distorted octahedral coordination geometry around the ZnII atom. The pterin ligand forms two chelate rings. The phen and pterin ring systems are nearly perpendicular [dihedral angle = 85.16 (5)°]. Classical N—H...O, O—H...N and O—H...O hydrogen bonds and weak C—H...O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. π–π stacking contacts are observed as well, with centroid-to-centroid distances of 3.5679 (14), 3.7004 (14), 3.6641 (15), 3.6974 (13) and 3.3412 (12) Å. |
| first_indexed | 2024-04-11T19:57:16Z |
| format | Article |
| id | doaj.art-a2ffbfadcac245769c846c26804ff0f7 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T19:57:16Z |
| publishDate | 2015-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-a2ffbfadcac245769c846c26804ff0f72022-12-22T04:05:58ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-09-01719m162m16310.1107/S2056989015014619xu5864Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrateSiddhartha S. Baisya0Baidyanath Ghosh1Parag S. Roy2Department of Chemistry, University of North Bengal, Siliguri 734 013, IndiaDepartment of Chemistry, University of North Bengal, Siliguri 734 013, IndiaDepartment of Chemistry, University of North Bengal, Siliguri 734 013, IndiaIn the title compound, [Zn(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate ligand, a bidentate ancillary 1,10-phenanthroline (phen) ligand and a water molecule complete a distorted octahedral coordination geometry around the ZnII atom. The pterin ligand forms two chelate rings. The phen and pterin ring systems are nearly perpendicular [dihedral angle = 85.16 (5)°]. Classical N—H...O, O—H...N and O—H...O hydrogen bonds and weak C—H...O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. π–π stacking contacts are observed as well, with centroid-to-centroid distances of 3.5679 (14), 3.7004 (14), 3.6641 (15), 3.6974 (13) and 3.3412 (12) Å.http://scripts.iucr.org/cgi-bin/paper?S2056989015014619crystal structurephenanthrolinezinc complexhydrogen bondingpteridineπ–π stacking |
| spellingShingle | Siddhartha S. Baisya Baidyanath Ghosh Parag S. Roy Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate Acta Crystallographica Section E: Crystallographic Communications crystal structure phenanthroline zinc complex hydrogen bonding pteridine π–π stacking |
| title | Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate |
| title_full | Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate |
| title_fullStr | Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate |
| title_full_unstemmed | Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate |
| title_short | Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate |
| title_sort | crystal structure of 2 amino 7 methyl 4 oxidopteridine 6 carboxylato κ3o4 n5 o6 aqua 1 10 phenanthroline κ2n n zinc trihydrate |
| topic | crystal structure phenanthroline zinc complex hydrogen bonding pteridine π–π stacking |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015014619 |
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