Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells

Crickets are gaining worldwide attention as a nutrient source with a low environmental impact. We considered crickets as a new source of chitin raw material. Chitin isolated from crickets was successfully converted to nanochitin by pulverization. First, chitin was obtained from cricket powder in a 2...

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Main Authors: Kana Kishida, Toshifumi Mizuta, Hironori Izawa, Shinsuke Ifuku
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/6/10/280
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author Kana Kishida
Toshifumi Mizuta
Hironori Izawa
Shinsuke Ifuku
author_facet Kana Kishida
Toshifumi Mizuta
Hironori Izawa
Shinsuke Ifuku
author_sort Kana Kishida
collection DOAJ
description Crickets are gaining worldwide attention as a nutrient source with a low environmental impact. We considered crickets as a new source of chitin raw material. Chitin isolated from crickets was successfully converted to nanochitin by pulverization. First, chitin was obtained from cricket powder in a 2.6% yield through a series of chemical treatments. Chitin identification was confirmed by FT-IR and <sup>13</sup>C NMR. The chitin had an α-type crystal structure and a deacetylation degree of 12%. Next, it was pulverized in a disk mill to obtain nanochitin. Cricket nanochitin was of a whisker shape, with an average fiber width of 10.1 nm. It was larger than that of crab shells, while the hydrodynamic diameter and crystal size were smaller. Such differences in shape affected the physical properties of the dispersion. The transmittance was higher than that of crab nanochitin due to the size effect, and the viscosity was smaller. Moreover, the dry non-woven cricket nanochitin sheets were more densely packed, and their modulus and breaking strength were greater.
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spelling doaj.art-a36786797fa547c4ac5b3d3cd7c6d30e2023-12-03T14:49:15ZengMDPI AGJournal of Composites Science2504-477X2022-09-0161028010.3390/jcs6100280Preparation of Nanochitin from Crickets and Comparison with That from Crab ShellsKana Kishida0Toshifumi Mizuta1Hironori Izawa2Shinsuke Ifuku3Graduate School of Engineering, Tottori University, 4-101 Koyama-Minami, Tottori 680-8550, JapanTechnical Department, Tottori University, Tottori 680-8550, JapanGraduate School of Engineering, Tottori University, 4-101 Koyama-Minami, Tottori 680-8550, JapanGraduate School of Engineering, Tottori University, 4-101 Koyama-Minami, Tottori 680-8550, JapanCrickets are gaining worldwide attention as a nutrient source with a low environmental impact. We considered crickets as a new source of chitin raw material. Chitin isolated from crickets was successfully converted to nanochitin by pulverization. First, chitin was obtained from cricket powder in a 2.6% yield through a series of chemical treatments. Chitin identification was confirmed by FT-IR and <sup>13</sup>C NMR. The chitin had an α-type crystal structure and a deacetylation degree of 12%. Next, it was pulverized in a disk mill to obtain nanochitin. Cricket nanochitin was of a whisker shape, with an average fiber width of 10.1 nm. It was larger than that of crab shells, while the hydrodynamic diameter and crystal size were smaller. Such differences in shape affected the physical properties of the dispersion. The transmittance was higher than that of crab nanochitin due to the size effect, and the viscosity was smaller. Moreover, the dry non-woven cricket nanochitin sheets were more densely packed, and their modulus and breaking strength were greater.https://www.mdpi.com/2504-477X/6/10/280nanochitincricketnanowhiskerreinforcing materialnanocomposite
spellingShingle Kana Kishida
Toshifumi Mizuta
Hironori Izawa
Shinsuke Ifuku
Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
Journal of Composites Science
nanochitin
cricket
nanowhisker
reinforcing material
nanocomposite
title Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
title_full Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
title_fullStr Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
title_full_unstemmed Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
title_short Preparation of Nanochitin from Crickets and Comparison with That from Crab Shells
title_sort preparation of nanochitin from crickets and comparison with that from crab shells
topic nanochitin
cricket
nanowhisker
reinforcing material
nanocomposite
url https://www.mdpi.com/2504-477X/6/10/280
work_keys_str_mv AT kanakishida preparationofnanochitinfromcricketsandcomparisonwiththatfromcrabshells
AT toshifumimizuta preparationofnanochitinfromcricketsandcomparisonwiththatfromcrabshells
AT hironoriizawa preparationofnanochitinfromcricketsandcomparisonwiththatfromcrabshells
AT shinsukeifuku preparationofnanochitinfromcricketsandcomparisonwiththatfromcrabshells