Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution

The ability of durian peel to remove Cd(II) ions from aqueous solution by biosorption was investigated. The sorption capacities at different solution pH, agitation speed, temperatures, initial cadmium ions concentrations and contact time were evaluated on a batch scale basis. At pH 5 and agitation...

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Main Authors: Wanna Saikaew, Pairat Kaewsarn
Format: Article
Language:English
Published: Environmental Research Institute, Chulalongkorn University 2013-06-01
Series:Applied Environmental Research
Subjects:
Online Access:https://ph01.tci-thaijo.org/index.php/aer/article/view/9697
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author Wanna Saikaew
Pairat Kaewsarn
author_facet Wanna Saikaew
Pairat Kaewsarn
author_sort Wanna Saikaew
collection DOAJ
description The ability of durian peel to remove Cd(II) ions from aqueous solution by biosorption was investigated. The sorption capacities at different solution pH, agitation speed, temperatures, initial cadmium ions concentrations and contact time were evaluated on a batch scale basis. At pH 5 and agitation speed 150 rpm, the cadmium ions removal reached at a maximum value. Increases in cadmium capacity with increasing temperature indicated endothermic nature of the biosorption process. The equilibrium was better described by the Langmuir isotherm model, with a maximum biosorption capacity of 18.55 mg g-1. The biosorption was relatively quick about 15 min to reach the equilibrium. Biosorption kinetics followed a pseudo-second-order model. Desorption experiments indicate that the desorption efficiency using 0.1 N HCl, HNO3 and H2SO4 aqueous solution were 96.58, 89.90 and 85.92 %, respectively. Fourier Transform Infrared Spectroscopy revealed that carboxyl, hydroxyl, and amide groups on the durian peels' surface involved in the adsorption of the cadmium ions as well as morphological aspects. Biosorption by durian peel has potential to serve as a remover of Cd(II) from wastewater.
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spelling doaj.art-a36dd088d31246f6891ae4a03def40842022-12-22T02:15:38ZengEnvironmental Research Institute, Chulalongkorn UniversityApplied Environmental Research2287-07412287-075X2013-06-01321Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous SolutionWanna Saikaew0Pairat Kaewsarn1Faculty of Engineering, Ubon Ratchathani University, Ubon Ratchathani, ThailandFaculty of Engineering, Ubon Ratchathani University, Ubon Ratchathani, Thailand The ability of durian peel to remove Cd(II) ions from aqueous solution by biosorption was investigated. The sorption capacities at different solution pH, agitation speed, temperatures, initial cadmium ions concentrations and contact time were evaluated on a batch scale basis. At pH 5 and agitation speed 150 rpm, the cadmium ions removal reached at a maximum value. Increases in cadmium capacity with increasing temperature indicated endothermic nature of the biosorption process. The equilibrium was better described by the Langmuir isotherm model, with a maximum biosorption capacity of 18.55 mg g-1. The biosorption was relatively quick about 15 min to reach the equilibrium. Biosorption kinetics followed a pseudo-second-order model. Desorption experiments indicate that the desorption efficiency using 0.1 N HCl, HNO3 and H2SO4 aqueous solution were 96.58, 89.90 and 85.92 %, respectively. Fourier Transform Infrared Spectroscopy revealed that carboxyl, hydroxyl, and amide groups on the durian peels' surface involved in the adsorption of the cadmium ions as well as morphological aspects. Biosorption by durian peel has potential to serve as a remover of Cd(II) from wastewater. https://ph01.tci-thaijo.org/index.php/aer/article/view/9697Durian peelBiosorptionCadmium ionsAgricultural waste
spellingShingle Wanna Saikaew
Pairat Kaewsarn
Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
Applied Environmental Research
Durian peel
Biosorption
Cadmium ions
Agricultural waste
title Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
title_full Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
title_fullStr Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
title_full_unstemmed Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
title_short Durian Peel as Biosorbent for Removal of Cadmium Ions from Aqueous Solution
title_sort durian peel as biosorbent for removal of cadmium ions from aqueous solution
topic Durian peel
Biosorption
Cadmium ions
Agricultural waste
url https://ph01.tci-thaijo.org/index.php/aer/article/view/9697
work_keys_str_mv AT wannasaikaew durianpeelasbiosorbentforremovalofcadmiumionsfromaqueoussolution
AT pairatkaewsarn durianpeelasbiosorbentforremovalofcadmiumionsfromaqueoussolution