Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption

In this study, keratins were extracted from pig nail waste via the reduction method for the first time, using L-cysteine as the reductant and urea as the lytic agent. Nylon6 and pig nail keratin were successfully combined via electrospinning to generate a series of nylon6/pig nail keratin nanofibers...

Full description

Bibliographic Details
Main Authors: Lanlan Wei, Di Wang, Zhiheng Liao, Zexuan Gong, Wenwen Zhao, Jinyan Gu, Yan Li, Jingjun Li
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/2/467
_version_ 1797437588745748480
author Lanlan Wei
Di Wang
Zhiheng Liao
Zexuan Gong
Wenwen Zhao
Jinyan Gu
Yan Li
Jingjun Li
author_facet Lanlan Wei
Di Wang
Zhiheng Liao
Zexuan Gong
Wenwen Zhao
Jinyan Gu
Yan Li
Jingjun Li
author_sort Lanlan Wei
collection DOAJ
description In this study, keratins were extracted from pig nail waste via the reduction method for the first time, using L-cysteine as the reductant and urea as the lytic agent. Nylon6 and pig nail keratin were successfully combined via electrospinning to generate a series of nylon6/pig nail keratin nanofibers with a variety of keratin concentrations (0% to 8%, <i>w</i>/<i>w</i>). From the results, it was found that the best concentration was 6% (<i>w</i>/<i>w</i>). The morphologies of the electrospun nanofibers were examined via scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structural properties were characterized using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD), and the thermal properties were described using thermo-gravimetric analysis (TGA). These results confirmed that the nanofibers were composed of both polymeric phases. Finally, copper (II) was used as a model ion, and the nanofiber membranes exhibited a strong adsorption affinity for metal ions in the water samples. This study provides an important foundation for the application of nanofiber membranes in metal adsorption.
first_indexed 2024-03-09T11:23:36Z
format Article
id doaj.art-a38b832da9dc4deab0a3c435365f6392
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-09T11:23:36Z
publishDate 2023-01-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-a38b832da9dc4deab0a3c435365f63922023-12-01T00:10:38ZengMDPI AGPolymers2073-43602023-01-0115246710.3390/polym15020467Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) AdsorptionLanlan Wei0Di Wang1Zhiheng Liao2Zexuan Gong3Wenwen Zhao4Jinyan Gu5Yan Li6Jingjun Li7College of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaCollege of Food Engineering, Anhui Science and Technology University, Chuzhou 233100, ChinaIn this study, keratins were extracted from pig nail waste via the reduction method for the first time, using L-cysteine as the reductant and urea as the lytic agent. Nylon6 and pig nail keratin were successfully combined via electrospinning to generate a series of nylon6/pig nail keratin nanofibers with a variety of keratin concentrations (0% to 8%, <i>w</i>/<i>w</i>). From the results, it was found that the best concentration was 6% (<i>w</i>/<i>w</i>). The morphologies of the electrospun nanofibers were examined via scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structural properties were characterized using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD), and the thermal properties were described using thermo-gravimetric analysis (TGA). These results confirmed that the nanofibers were composed of both polymeric phases. Finally, copper (II) was used as a model ion, and the nanofiber membranes exhibited a strong adsorption affinity for metal ions in the water samples. This study provides an important foundation for the application of nanofiber membranes in metal adsorption.https://www.mdpi.com/2073-4360/15/2/467pig nailskeratinelectrospinningnanofibercopper (II) ion adsorption
spellingShingle Lanlan Wei
Di Wang
Zhiheng Liao
Zexuan Gong
Wenwen Zhao
Jinyan Gu
Yan Li
Jingjun Li
Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
Polymers
pig nails
keratin
electrospinning
nanofiber
copper (II) ion adsorption
title Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
title_full Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
title_fullStr Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
title_full_unstemmed Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
title_short Extraction of Keratin from Pig Nails and Electrospinning of Keratin/Nylon6 Nanofibers for Copper (II) Adsorption
title_sort extraction of keratin from pig nails and electrospinning of keratin nylon6 nanofibers for copper ii adsorption
topic pig nails
keratin
electrospinning
nanofiber
copper (II) ion adsorption
url https://www.mdpi.com/2073-4360/15/2/467
work_keys_str_mv AT lanlanwei extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT diwang extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT zhihengliao extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT zexuangong extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT wenwenzhao extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT jinyangu extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT yanli extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption
AT jingjunli extractionofkeratinfrompignailsandelectrospinningofkeratinnylon6nanofibersforcopperiiadsorption