Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks

Controlling the charge transfer between radical anions and cations is a promising way to tune the emission mechanism in electrochemiluminescence (ECL) systems. Here, the authors report a donor-acceptor based covalent organic framework, using triphenylamine and triazine building units, and demonstrat...

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Main Authors: Rengan Luo, Haifeng Lv, Qiaobo Liao, Ningning Wang, Jiarui Yang, Yang Li, Kai Xi, Xiaojun Wu, Huangxian Ju, Jianping Lei
Format: Article
Language:English
Published: Nature Portfolio 2021-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-27127-5
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author Rengan Luo
Haifeng Lv
Qiaobo Liao
Ningning Wang
Jiarui Yang
Yang Li
Kai Xi
Xiaojun Wu
Huangxian Ju
Jianping Lei
author_facet Rengan Luo
Haifeng Lv
Qiaobo Liao
Ningning Wang
Jiarui Yang
Yang Li
Kai Xi
Xiaojun Wu
Huangxian Ju
Jianping Lei
author_sort Rengan Luo
collection DOAJ
description Controlling the charge transfer between radical anions and cations is a promising way to tune the emission mechanism in electrochemiluminescence (ECL) systems. Here, the authors report a donor-acceptor based covalent organic framework, using triphenylamine and triazine building units, and demonstrate efficient ECL based on an adjustable intrareticular charge transfer.
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spelling doaj.art-a39b320f08a34299b80aab694c749b042022-12-21T22:56:05ZengNature PortfolioNature Communications2041-17232021-11-011211910.1038/s41467-021-27127-5Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworksRengan Luo0Haifeng Lv1Qiaobo Liao2Ningning Wang3Jiarui Yang4Yang Li5Kai Xi6Xiaojun Wu7Huangxian Ju8Jianping Lei9State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversityHefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation of Quantum Information and Quantum Technology, CAS Center for Excellence in Nanoscience, and School of Chemistry and Materials Sciences, University of Science and Technology of ChinaSchool of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversitySchool of Chemistry and Chemical Engineering, Nanjing UniversityHefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation of Quantum Information and Quantum Technology, CAS Center for Excellence in Nanoscience, and School of Chemistry and Materials Sciences, University of Science and Technology of ChinaState Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing UniversityControlling the charge transfer between radical anions and cations is a promising way to tune the emission mechanism in electrochemiluminescence (ECL) systems. Here, the authors report a donor-acceptor based covalent organic framework, using triphenylamine and triazine building units, and demonstrate efficient ECL based on an adjustable intrareticular charge transfer.https://doi.org/10.1038/s41467-021-27127-5
spellingShingle Rengan Luo
Haifeng Lv
Qiaobo Liao
Ningning Wang
Jiarui Yang
Yang Li
Kai Xi
Xiaojun Wu
Huangxian Ju
Jianping Lei
Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
Nature Communications
title Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
title_full Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
title_fullStr Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
title_full_unstemmed Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
title_short Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks
title_sort intrareticular charge transfer regulated electrochemiluminescence of donor acceptor covalent organic frameworks
url https://doi.org/10.1038/s41467-021-27127-5
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