Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III)
A simple and sensitive solid-phase spectrophotometric method was developed for the determination of rhodium(III) trace amounts. The proposed procedure is based on the reaction product of disodium-1-nitroso-2-hydroxynaphthalene-3,6-disulfonate(Nitroso R salt) previously loaded on Dowex 1×1 anion exch...
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| Format: | Article |
| Language: | English |
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De Gruyter
2011-11-01
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| Series: | Reviews in Analytical Chemistry |
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| Online Access: | https://doi.org/10.1515/REVAC.2011.103 |
| _version_ | 1818584524957679616 |
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| author | Tofan Lavinia |
| author_facet | Tofan Lavinia |
| author_sort | Tofan Lavinia |
| collection | DOAJ |
| description | A simple and sensitive solid-phase spectrophotometric method was developed for the determination of rhodium(III) trace amounts. The proposed procedure is based on the reaction product of disodium-1-nitroso-2-hydroxynaphthalene-3,6-disulfonate(Nitroso R salt) previously loaded on Dowex 1×1 anion exchanger. To find the best analytical conditions for the determination, the experimental variables (wavelength, pH, amount of resin, sample solution volume) were optimized. Under the selected conditions, rhodium(III) can be accurately determined in the range of 0.5–2 μg/ml with an RSD of 1.18% and a degree of sensitivity, expressed by the molar absorptivity, of 3.0356×104 l/mol cm. The results obtained on synthetic solutions clearly indicate the feasibility of the proposed method for real sample analysis. |
| first_indexed | 2024-12-16T08:22:33Z |
| format | Article |
| id | doaj.art-a3b19090fd6a449a9f1c874e10c6cc32 |
| institution | Directory Open Access Journal |
| issn | 0793-0135 2191-0189 |
| language | English |
| last_indexed | 2024-12-16T08:22:33Z |
| publishDate | 2011-11-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Reviews in Analytical Chemistry |
| spelling | doaj.art-a3b19090fd6a449a9f1c874e10c6cc322022-12-21T22:38:05ZengDe GruyterReviews in Analytical Chemistry0793-01352191-01892011-11-01303-417117510.1515/REVAC.2011.103Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III)Tofan Lavinia0Department of Environmental Engineering and Management, Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iasi, 71 D. Mangeron Street, 700050 Iasi, RomaniaA simple and sensitive solid-phase spectrophotometric method was developed for the determination of rhodium(III) trace amounts. The proposed procedure is based on the reaction product of disodium-1-nitroso-2-hydroxynaphthalene-3,6-disulfonate(Nitroso R salt) previously loaded on Dowex 1×1 anion exchanger. To find the best analytical conditions for the determination, the experimental variables (wavelength, pH, amount of resin, sample solution volume) were optimized. Under the selected conditions, rhodium(III) can be accurately determined in the range of 0.5–2 μg/ml with an RSD of 1.18% and a degree of sensitivity, expressed by the molar absorptivity, of 3.0356×104 l/mol cm. The results obtained on synthetic solutions clearly indicate the feasibility of the proposed method for real sample analysis.https://doi.org/10.1515/REVAC.2011.103determinationnitroso r saltrhodiumsolid-phase spectrophotometry |
| spellingShingle | Tofan Lavinia Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) Reviews in Analytical Chemistry determination nitroso r salt rhodium solid-phase spectrophotometry |
| title | Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) |
| title_full | Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) |
| title_fullStr | Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) |
| title_full_unstemmed | Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) |
| title_short | Solid-phase spectrophotometry use for the determination of trace amounts of Rh(III) |
| title_sort | solid phase spectrophotometry use for the determination of trace amounts of rh iii |
| topic | determination nitroso r salt rhodium solid-phase spectrophotometry |
| url | https://doi.org/10.1515/REVAC.2011.103 |
| work_keys_str_mv | AT tofanlavinia solidphasespectrophotometryuseforthedeterminationoftraceamountsofrhiii |