Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification

Phosphogypsum (PG) treatment is one of the research hotspots in the field of environmental protection. Many researchers both at home and abroad have devoted themselves to studies on harmless resource treatment of PG, but the treatment technology is unable to meet the demand of PG consumption due to...

Full description

Bibliographic Details
Main Authors: Fenghui Wu, Can Yang, Guangfei Qu, Liangliang Liu, Bangjin Chen, Shan Liu, Junyan Li, Yuanchuan Ren, Yuyi Yang
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/2/462
_version_ 1797491569548328960
author Fenghui Wu
Can Yang
Guangfei Qu
Liangliang Liu
Bangjin Chen
Shan Liu
Junyan Li
Yuanchuan Ren
Yuyi Yang
author_facet Fenghui Wu
Can Yang
Guangfei Qu
Liangliang Liu
Bangjin Chen
Shan Liu
Junyan Li
Yuanchuan Ren
Yuyi Yang
author_sort Fenghui Wu
collection DOAJ
description Phosphogypsum (PG) treatment is one of the research hotspots in the field of environmental protection. Many researchers both at home and abroad have devoted themselves to studies on harmless resource treatment of PG, but the treatment technology is unable to meet the demand of PG consumption due to the huge production and storage demands. In order to solve the problem of PG pollution, this study explored the different solidified effects of various modification formulations on the hazardous components in PG, using industrial solid waste calcium carbide slag (CCS) as an alkaline regulator; Portland cement (PC), polyaluminum chloride (PAC) and CaCl<sub>2</sub> as the main raw materials of the solidification and stabilization formula and the water content in PG as the reaction medium. The results showed that CCS (0.5%), PC (0.4%) and PAC (0.3%) had a more significant solidified effect on phosphorus (P) and fluoride (F). PAC was added in two steps and reacted under normal temperature and pressure, and its leaching toxicity meets the requirements of relevant standards, which laid an excellent foundation for PG-based ecological restoration materials and filling materials, with low economic cost, simple process and strong feasibility. This will provide great convenience for the later mining and metallurgy.
first_indexed 2024-03-10T00:50:10Z
format Article
id doaj.art-a3be35e08a7842ea9a5204ae29f981ad
institution Directory Open Access Journal
issn 1420-3049
language English
last_indexed 2024-03-10T00:50:10Z
publishDate 2022-01-01
publisher MDPI AG
record_format Article
series Molecules
spelling doaj.art-a3be35e08a7842ea9a5204ae29f981ad2023-11-23T14:52:19ZengMDPI AGMolecules1420-30492022-01-0127246210.3390/molecules27020462Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by ModificationFenghui Wu0Can Yang1Guangfei Qu2Liangliang Liu3Bangjin Chen4Shan Liu5Junyan Li6Yuanchuan Ren7Yuyi Yang8Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaFaculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, ChinaPhosphogypsum (PG) treatment is one of the research hotspots in the field of environmental protection. Many researchers both at home and abroad have devoted themselves to studies on harmless resource treatment of PG, but the treatment technology is unable to meet the demand of PG consumption due to the huge production and storage demands. In order to solve the problem of PG pollution, this study explored the different solidified effects of various modification formulations on the hazardous components in PG, using industrial solid waste calcium carbide slag (CCS) as an alkaline regulator; Portland cement (PC), polyaluminum chloride (PAC) and CaCl<sub>2</sub> as the main raw materials of the solidification and stabilization formula and the water content in PG as the reaction medium. The results showed that CCS (0.5%), PC (0.4%) and PAC (0.3%) had a more significant solidified effect on phosphorus (P) and fluoride (F). PAC was added in two steps and reacted under normal temperature and pressure, and its leaching toxicity meets the requirements of relevant standards, which laid an excellent foundation for PG-based ecological restoration materials and filling materials, with low economic cost, simple process and strong feasibility. This will provide great convenience for the later mining and metallurgy.https://www.mdpi.com/1420-3049/27/2/462phosphogypsummodificationleaching toxicitysemi-drysolidification/stabilization
spellingShingle Fenghui Wu
Can Yang
Guangfei Qu
Liangliang Liu
Bangjin Chen
Shan Liu
Junyan Li
Yuanchuan Ren
Yuyi Yang
Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
Molecules
phosphogypsum
modification
leaching toxicity
semi-dry
solidification/stabilization
title Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
title_full Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
title_fullStr Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
title_full_unstemmed Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
title_short Study of Semi-Dry High Target Solidification/Stabilization of Harmful Impurities in Phosphogypsum by Modification
title_sort study of semi dry high target solidification stabilization of harmful impurities in phosphogypsum by modification
topic phosphogypsum
modification
leaching toxicity
semi-dry
solidification/stabilization
url https://www.mdpi.com/1420-3049/27/2/462
work_keys_str_mv AT fenghuiwu studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT canyang studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT guangfeiqu studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT liangliangliu studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT bangjinchen studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT shanliu studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT junyanli studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT yuanchuanren studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification
AT yuyiyang studyofsemidryhightargetsolidificationstabilizationofharmfulimpuritiesinphosphogypsumbymodification