Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan
Cellulose and chitosan are natural polymers that have been used as biocomposite. The aim of this research is to obtain biofilms from chitosan and oxidized cellulose crosslinks. This research is divided into three steps, i.e., isolation of cellulose from oil palm trunk and oxidation of cellulose usin...
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Format: | Article |
Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2019-04-01
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Series: | Indonesian Journal of Chemistry |
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Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/34721 |
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author | Agung Pratama Firman Sebayang Rumondang Bulan Nasution |
author_facet | Agung Pratama Firman Sebayang Rumondang Bulan Nasution |
author_sort | Agung Pratama |
collection | DOAJ |
description | Cellulose and chitosan are natural polymers that have been used as biocomposite. The aim of this research is to obtain biofilms from chitosan and oxidized cellulose crosslinks. This research is divided into three steps, i.e., isolation of cellulose from oil palm trunk and oxidation of cellulose using NaIO4 (0.2; 0.4; 0.6; 0.8; 1.0 mg/mL) to obtain dialdehyde cellulose (DAC), crosslink of oxidized cellulose with chitosan (DD = 72.85%) to obtain biofilm of chitosan/DAC (CDAC), and characterization of biofilms. The crosslinked reaction was confirmed by FT-IR analysis that showed the spectrum of Schiff base C=N group at 1651 cm–1. Tensile strength increased gradually when the NaIO4 concentration used was 0.2–0.6 mg/mL, but after those concentrations, the tensile strength slightly decreased. The morphology analysis showed that CDAC had smoother morphology than DAC, which was shown rough and showed some particle indicated the presence of unreacted cellulose. CDAC biofilms that prepared with 1.0 mg/mL NaIO4 showed the greatest antibacterial activity. |
first_indexed | 2024-12-19T03:20:53Z |
format | Article |
id | doaj.art-a3d008418f6341ee9667f225120b8a29 |
institution | Directory Open Access Journal |
issn | 1411-9420 2460-1578 |
language | English |
last_indexed | 2024-12-19T03:20:53Z |
publishDate | 2019-04-01 |
publisher | Department of Chemistry, Universitas Gadjah Mada |
record_format | Article |
series | Indonesian Journal of Chemistry |
spelling | doaj.art-a3d008418f6341ee9667f225120b8a292022-12-21T20:37:47ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782019-04-0119240541210.22146/ijc.3472122933Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and ChitosanAgung Pratama0Firman Sebayang1Rumondang Bulan Nasution2Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Sumatera Utara, Jl. Bioteknologi No.1, Kampus USU, Medan 20155, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Sumatera Utara, Jl. Bioteknologi No.1, Kampus USU, Medan 20155, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Sumatera Utara, Jl. Bioteknologi No.1, Kampus USU, Medan 20155, IndonesiaCellulose and chitosan are natural polymers that have been used as biocomposite. The aim of this research is to obtain biofilms from chitosan and oxidized cellulose crosslinks. This research is divided into three steps, i.e., isolation of cellulose from oil palm trunk and oxidation of cellulose using NaIO4 (0.2; 0.4; 0.6; 0.8; 1.0 mg/mL) to obtain dialdehyde cellulose (DAC), crosslink of oxidized cellulose with chitosan (DD = 72.85%) to obtain biofilm of chitosan/DAC (CDAC), and characterization of biofilms. The crosslinked reaction was confirmed by FT-IR analysis that showed the spectrum of Schiff base C=N group at 1651 cm–1. Tensile strength increased gradually when the NaIO4 concentration used was 0.2–0.6 mg/mL, but after those concentrations, the tensile strength slightly decreased. The morphology analysis showed that CDAC had smoother morphology than DAC, which was shown rough and showed some particle indicated the presence of unreacted cellulose. CDAC biofilms that prepared with 1.0 mg/mL NaIO4 showed the greatest antibacterial activity.https://jurnal.ugm.ac.id/ijc/article/view/34721biofilmcellulosechitosandialdehyde cellulose, Schiff base |
spellingShingle | Agung Pratama Firman Sebayang Rumondang Bulan Nasution Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan Indonesian Journal of Chemistry biofilm cellulose chitosan dialdehyde cellulose, Schiff base |
title | Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan |
title_full | Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan |
title_fullStr | Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan |
title_full_unstemmed | Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan |
title_short | Antibacterial Properties of Biofilm Schiff Base Derived from Dialdehyde Cellulose and Chitosan |
title_sort | antibacterial properties of biofilm schiff base derived from dialdehyde cellulose and chitosan |
topic | biofilm cellulose chitosan dialdehyde cellulose, Schiff base |
url | https://jurnal.ugm.ac.id/ijc/article/view/34721 |
work_keys_str_mv | AT agungpratama antibacterialpropertiesofbiofilmschiffbasederivedfromdialdehydecelluloseandchitosan AT firmansebayang antibacterialpropertiesofbiofilmschiffbasederivedfromdialdehydecelluloseandchitosan AT rumondangbulannasution antibacterialpropertiesofbiofilmschiffbasederivedfromdialdehydecelluloseandchitosan |