Summary: | In this manuscript, the nonlinear absorption properties of Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> and its application in ultra-fast optical modulation are investigated. Typical parameters, namely, nonlinear absorption coefficient (β), saturation intensity, and modulation depth are measured to be ~1.66 × 10<sup>−9</sup> m/W, 15.3 MW/cm<sup>2</sup>, and 5.8%, respectively. To investigate the feasibility of using the Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> as an ultra-fast optical modulator, a ring-cavity passively mode-locked Er-doped fiber laser has been constructed. The output power/pulse, duration/pulse, and repetition rate/signal-to-noise ratios for the stable mode-locked operation are 2.88 mW/881 fs/19.33 MHz/48 dB, respectively, which proves that the Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> has outstanding nonlinear optical properties and advantages in performing as an ultra-fast optical modulator. Further, the experimental results provide valuable references and open new avenues for developing two-dimensional, material-based, ultra-fast optical modulators and advanced photonic devices based on Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub>.
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