Controlled transitions between metastable states of 2D magnetocapillary crystals

Abstract Magnetocapillary interactions between particles allow to self-assemble floating crystals along liquid interfaces. For a fixed number of particles, different states possessing different symmetrical features, known as metastable states, coexist. In this paper, we demonstrate how to trigger th...

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Main Authors: Ylona Collard, Franco N. Piñan Basualdo, Aude Bolopion, Michaël Gauthier, Pierre Lambert, Nicolas Vandewalle
Format: Article
Language:English
Published: Nature Portfolio 2022-09-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-20035-8
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author Ylona Collard
Franco N. Piñan Basualdo
Aude Bolopion
Michaël Gauthier
Pierre Lambert
Nicolas Vandewalle
author_facet Ylona Collard
Franco N. Piñan Basualdo
Aude Bolopion
Michaël Gauthier
Pierre Lambert
Nicolas Vandewalle
author_sort Ylona Collard
collection DOAJ
description Abstract Magnetocapillary interactions between particles allow to self-assemble floating crystals along liquid interfaces. For a fixed number of particles, different states possessing different symmetrical features, known as metastable states, coexist. In this paper, we demonstrate how to trigger the transition from one state to another, either by rearranging the crystal, or by controlling its growth. First, we show that externally controlled magnetic fields can squeeze the entire crystal to induce structural modifications, that upon relaxation can lead to a modified state. Second, we propose localized laser-induced thermocapillary flows that can be used to guide new particles towards an existing crystal in a desired direction, thus favoring a particular resulting state. The control of the formation of metastable states is a key ingredient to functionalize such assemblies, paving the way to self-assembled microrobots.
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spelling doaj.art-a40eb28d80bd44808ecc9c9add09503f2022-12-22T03:24:19ZengNature PortfolioScientific Reports2045-23222022-09-011211910.1038/s41598-022-20035-8Controlled transitions between metastable states of 2D magnetocapillary crystalsYlona Collard0Franco N. Piñan Basualdo1Aude Bolopion2Michaël Gauthier3Pierre Lambert4Nicolas Vandewalle5GRASP, Institute of Physics B5a, Université de LiègeTIPs, École Polytechnique de Bruxelles, Université Libre de BruxelleFEMTO-ST, CNRS, Université Bourgogne Franche-ComtéFEMTO-ST, CNRS, Université Bourgogne Franche-ComtéTIPs, École Polytechnique de Bruxelles, Université Libre de BruxelleGRASP, Institute of Physics B5a, Université de LiègeAbstract Magnetocapillary interactions between particles allow to self-assemble floating crystals along liquid interfaces. For a fixed number of particles, different states possessing different symmetrical features, known as metastable states, coexist. In this paper, we demonstrate how to trigger the transition from one state to another, either by rearranging the crystal, or by controlling its growth. First, we show that externally controlled magnetic fields can squeeze the entire crystal to induce structural modifications, that upon relaxation can lead to a modified state. Second, we propose localized laser-induced thermocapillary flows that can be used to guide new particles towards an existing crystal in a desired direction, thus favoring a particular resulting state. The control of the formation of metastable states is a key ingredient to functionalize such assemblies, paving the way to self-assembled microrobots.https://doi.org/10.1038/s41598-022-20035-8
spellingShingle Ylona Collard
Franco N. Piñan Basualdo
Aude Bolopion
Michaël Gauthier
Pierre Lambert
Nicolas Vandewalle
Controlled transitions between metastable states of 2D magnetocapillary crystals
Scientific Reports
title Controlled transitions between metastable states of 2D magnetocapillary crystals
title_full Controlled transitions between metastable states of 2D magnetocapillary crystals
title_fullStr Controlled transitions between metastable states of 2D magnetocapillary crystals
title_full_unstemmed Controlled transitions between metastable states of 2D magnetocapillary crystals
title_short Controlled transitions between metastable states of 2D magnetocapillary crystals
title_sort controlled transitions between metastable states of 2d magnetocapillary crystals
url https://doi.org/10.1038/s41598-022-20035-8
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