CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries

Abstract CoFe2O4-graphene nanosheets (CoFe2O4-GNSs) were synthesized through an ultrasonic method, and their electrochemical performances as Li-ion battery electrode were improved by annealing processes. The nanocomposites obtained at 350 °C maintained a high specific capacity of 1,257 mAh g−1 even...

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Main Authors: Yinglin Xiao, Xiaomin Li, Jiantao Zai, Kaixue Wang, Yong Gong, Bo Li, Qianyan Han, Xuefeng Qian
Format: Article
Language:English
Published: SpringerOpen 2014-09-01
Series:Nano-Micro Letters
Subjects:
Online Access:https://doi.org/10.1007/s40820-014-0003-7
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author Yinglin Xiao
Xiaomin Li
Jiantao Zai
Kaixue Wang
Yong Gong
Bo Li
Qianyan Han
Xuefeng Qian
author_facet Yinglin Xiao
Xiaomin Li
Jiantao Zai
Kaixue Wang
Yong Gong
Bo Li
Qianyan Han
Xuefeng Qian
author_sort Yinglin Xiao
collection DOAJ
description Abstract CoFe2O4-graphene nanosheets (CoFe2O4-GNSs) were synthesized through an ultrasonic method, and their electrochemical performances as Li-ion battery electrode were improved by annealing processes. The nanocomposites obtained at 350 °C maintained a high specific capacity of 1,257 mAh g−1 even after 200 cycles at 0.1 A g−1. Furthermore, the obtained materials also have better rate capability, and it can be maintained to 696, 495, 308, and 254 mAh g−1 at 1, 2, 5, and 10 A g−1, respectively. The enhancements realized in the reversible capacity and cyclic stability can be attributed to the good improvement in the electrical conductivity achieved by annealing at appropriate temperature, and the electrochemical nature of CoFe2O4 and GNSs during discharge–charge processes. Graphical Abstract CoFe2O4-graphene nanocomposites (CoFe2O4-GNSs) have been synthesized through an ultrasonic method combined with calcination process. The nanocomposite calcinated at 350 °C shows better rate capabilities, e.g., 696, 495, 308, and 254 mAh g−1 at 1, 2, 5, and 10 A g−1, respectively.
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spelling doaj.art-a41d6f25b9bc40db8ff2c5cf73adbe482024-01-07T12:40:49ZengSpringerOpenNano-Micro Letters2311-67062150-55512014-09-016430731510.1007/s40820-014-0003-7CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion BatteriesYinglin Xiao0Xiaomin Li1Jiantao Zai2Kaixue Wang3Yong Gong4Bo Li5Qianyan Han6Xuefeng Qian7School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversitySchool of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong UniversityAbstract CoFe2O4-graphene nanosheets (CoFe2O4-GNSs) were synthesized through an ultrasonic method, and their electrochemical performances as Li-ion battery electrode were improved by annealing processes. The nanocomposites obtained at 350 °C maintained a high specific capacity of 1,257 mAh g−1 even after 200 cycles at 0.1 A g−1. Furthermore, the obtained materials also have better rate capability, and it can be maintained to 696, 495, 308, and 254 mAh g−1 at 1, 2, 5, and 10 A g−1, respectively. The enhancements realized in the reversible capacity and cyclic stability can be attributed to the good improvement in the electrical conductivity achieved by annealing at appropriate temperature, and the electrochemical nature of CoFe2O4 and GNSs during discharge–charge processes. Graphical Abstract CoFe2O4-graphene nanocomposites (CoFe2O4-GNSs) have been synthesized through an ultrasonic method combined with calcination process. The nanocomposite calcinated at 350 °C shows better rate capabilities, e.g., 696, 495, 308, and 254 mAh g−1 at 1, 2, 5, and 10 A g−1, respectively.https://doi.org/10.1007/s40820-014-0003-7Cobalt ferriteGrapheneAnode materialsLithium ion battery
spellingShingle Yinglin Xiao
Xiaomin Li
Jiantao Zai
Kaixue Wang
Yong Gong
Bo Li
Qianyan Han
Xuefeng Qian
CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
Nano-Micro Letters
Cobalt ferrite
Graphene
Anode materials
Lithium ion battery
title CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
title_full CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
title_fullStr CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
title_full_unstemmed CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
title_short CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries
title_sort cofe2o4 graphene nanocomposites synthesized through an ultrasonic method with enhanced performances as anode materials for li ion batteries
topic Cobalt ferrite
Graphene
Anode materials
Lithium ion battery
url https://doi.org/10.1007/s40820-014-0003-7
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