THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES

The complexes of composition [SnL2] have been obtained by SnCl4 interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methano...

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Main Authors: N. V. Shmatkova, G. V. Yalovskiy, I. I. Seyfullina, A. A. Polishuk, A. V. Mazepa
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2014-12-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
Subjects:
Online Access:http://heraldchem.onu.edu.ua/article/view/31725
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author N. V. Shmatkova
G. V. Yalovskiy
I. I. Seyfullina
A. A. Polishuk
A. V. Mazepa
author_facet N. V. Shmatkova
G. V. Yalovskiy
I. I. Seyfullina
A. A. Polishuk
A. V. Mazepa
author_sort N. V. Shmatkova
collection DOAJ
description The complexes of composition [SnL2] have been obtained by SnCl4 interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methanol with the addition of ammonia solution). It was proved by methods of mass, electronic and IR spectroscopy ligands molecules to be coordinated by tin atom as tridentate ones via azomethine group nitrogen atom and enol and oxy-groups oxygen atoms. The thermal stability of obtained compounds has been studied. The structure schemes are offered.
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spelling doaj.art-a41d7e5a09054c51b19879c11d524d582022-12-22T00:25:56ZengOdessa I. I. Mechnikov National UniversityVìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632014-12-01174(44)51410.18524/2304-0947.2012.4(44).3172531725THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONESN. V. Shmatkova0G. V. Yalovskiy1I. I. Seyfullina2A. A. Polishuk3A. V. Mazepa4Одеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаТОВ «Інфокс»Фізико-хімічний інститут імені О. В. Богатського НАН УкраїниThe complexes of composition [SnL2] have been obtained by SnCl4 interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methanol with the addition of ammonia solution). It was proved by methods of mass, electronic and IR spectroscopy ligands molecules to be coordinated by tin atom as tridentate ones via azomethine group nitrogen atom and enol and oxy-groups oxygen atoms. The thermal stability of obtained compounds has been studied. The structure schemes are offered.http://heraldchem.onu.edu.ua/article/view/31725кислота Льюїса (SnCl4 )станум(IV)гідразоникоординаційні сполуки
spellingShingle N. V. Shmatkova
G. V. Yalovskiy
I. I. Seyfullina
A. A. Polishuk
A. V. Mazepa
THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
кислота Льюїса (SnCl4 )
станум(IV)
гідразони
координаційні сполуки
title THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
title_full THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
title_fullStr THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
title_full_unstemmed THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
title_short THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
title_sort formation properties and composition of tin iv complexes with 2 hydroxybenz 1 naphth aldehydes aroylhydrazones
topic кислота Льюїса (SnCl4 )
станум(IV)
гідразони
координаційні сполуки
url http://heraldchem.onu.edu.ua/article/view/31725
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