THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES
The complexes of composition [SnL2] have been obtained by SnCl4 interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methano...
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Odessa I. I. Mechnikov National University
2014-12-01
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Series: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
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Online Access: | http://heraldchem.onu.edu.ua/article/view/31725 |
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author | N. V. Shmatkova G. V. Yalovskiy I. I. Seyfullina A. A. Polishuk A. V. Mazepa |
author_facet | N. V. Shmatkova G. V. Yalovskiy I. I. Seyfullina A. A. Polishuk A. V. Mazepa |
author_sort | N. V. Shmatkova |
collection | DOAJ |
description | The complexes of composition [SnL2] have been obtained by SnCl4
interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methanol with the addition of ammonia solution). It was proved by methods of mass, electronic and IR spectroscopy ligands molecules to be coordinated by tin atom as tridentate ones via azomethine group
nitrogen atom and enol and oxy-groups oxygen atoms. The thermal stability of obtained compounds has been studied. The structure schemes are offered. |
first_indexed | 2024-12-12T11:25:27Z |
format | Article |
id | doaj.art-a41d7e5a09054c51b19879c11d524d58 |
institution | Directory Open Access Journal |
issn | 2304-0947 2414-5963 |
language | English |
last_indexed | 2024-12-12T11:25:27Z |
publishDate | 2014-12-01 |
publisher | Odessa I. I. Mechnikov National University |
record_format | Article |
series | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
spelling | doaj.art-a41d7e5a09054c51b19879c11d524d582022-12-22T00:25:56ZengOdessa I. I. Mechnikov National UniversityVìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632014-12-01174(44)51410.18524/2304-0947.2012.4(44).3172531725THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONESN. V. Shmatkova0G. V. Yalovskiy1I. I. Seyfullina2A. A. Polishuk3A. V. Mazepa4Одеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаТОВ «Інфокс»Фізико-хімічний інститут імені О. В. Богатського НАН УкраїниThe complexes of composition [SnL2] have been obtained by SnCl4 interaction with 2-hydroxybenz-(-1-naphth)aldehydes benzoyl-(2-hydroxybenzoyl)hydrazones (2-naphthoyl-(3-hydroxy-2-naphthoyl)hydrazones) (Н2L) in aqua-organic and low alkali media (ethanol in the presence of sodium ethylate and methanol with the addition of ammonia solution). It was proved by methods of mass, electronic and IR spectroscopy ligands molecules to be coordinated by tin atom as tridentate ones via azomethine group nitrogen atom and enol and oxy-groups oxygen atoms. The thermal stability of obtained compounds has been studied. The structure schemes are offered.http://heraldchem.onu.edu.ua/article/view/31725кислота Льюїса (SnCl4 )станум(IV)гідразоникоординаційні сполуки |
spellingShingle | N. V. Shmatkova G. V. Yalovskiy I. I. Seyfullina A. A. Polishuk A. V. Mazepa THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ кислота Льюїса (SnCl4 ) станум(IV) гідразони координаційні сполуки |
title | THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES |
title_full | THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES |
title_fullStr | THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES |
title_full_unstemmed | THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES |
title_short | THE FORMATION, PROPERTIES AND COMPOSITION OF TIN(IV) COMPLEXES WITH 2‑HYDROXYBENZ‑(‑1‑NAPHTH) ALDEHYDES AROYLHYDRAZONES |
title_sort | formation properties and composition of tin iv complexes with 2 hydroxybenz 1 naphth aldehydes aroylhydrazones |
topic | кислота Льюїса (SnCl4 ) станум(IV) гідразони координаційні сполуки |
url | http://heraldchem.onu.edu.ua/article/view/31725 |
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