Formose reaction controlled by boronic acid compounds
Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided differ...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2016-12-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.12.263 |
| _version_ | 1819062894427373568 |
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| author | Toru Imai Tomohiro Michitaka Akihito Hashidzume |
| author_facet | Toru Imai Tomohiro Michitaka Akihito Hashidzume |
| author_sort | Toru Imai |
| collection | DOAJ |
| description | Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided different selectivities; sugars of a small carbon number were formed favorably in the presence of SPB, whereas sugar alcohols of a larger carbon number were formed preferably in the presence of pVPB/NaSS. |
| first_indexed | 2024-12-21T15:06:02Z |
| format | Article |
| id | doaj.art-a447027f384d46a193b40d510cdf8655 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-21T15:06:02Z |
| publishDate | 2016-12-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-a447027f384d46a193b40d510cdf86552022-12-21T18:59:27ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-12-011212668267210.3762/bjoc.12.2631860-5397-12-263Formose reaction controlled by boronic acid compoundsToru Imai0Tomohiro Michitaka1Akihito Hashidzume2Department of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, JapanFormose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided different selectivities; sugars of a small carbon number were formed favorably in the presence of SPB, whereas sugar alcohols of a larger carbon number were formed preferably in the presence of pVPB/NaSS.https://doi.org/10.3762/bjoc.12.263boronic acid compoundsformose reactionsodium phenylboronatesodium 4-vinylphenylboronate/sodium 4-styrenesulfonate copolymersugar alcoholssugars |
| spellingShingle | Toru Imai Tomohiro Michitaka Akihito Hashidzume Formose reaction controlled by boronic acid compounds Beilstein Journal of Organic Chemistry boronic acid compounds formose reaction sodium phenylboronate sodium 4-vinylphenylboronate/sodium 4-styrenesulfonate copolymer sugar alcohols sugars |
| title | Formose reaction controlled by boronic acid compounds |
| title_full | Formose reaction controlled by boronic acid compounds |
| title_fullStr | Formose reaction controlled by boronic acid compounds |
| title_full_unstemmed | Formose reaction controlled by boronic acid compounds |
| title_short | Formose reaction controlled by boronic acid compounds |
| title_sort | formose reaction controlled by boronic acid compounds |
| topic | boronic acid compounds formose reaction sodium phenylboronate sodium 4-vinylphenylboronate/sodium 4-styrenesulfonate copolymer sugar alcohols sugars |
| url | https://doi.org/10.3762/bjoc.12.263 |
| work_keys_str_mv | AT toruimai formosereactioncontrolledbyboronicacidcompounds AT tomohiromichitaka formosereactioncontrolledbyboronicacidcompounds AT akihitohashidzume formosereactioncontrolledbyboronicacidcompounds |