2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
The asymmetric unit of the title compound, C18H14ClNO3, contains two independent molecules (A and B). In both molecules, the cyclohexanone ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chlorophenyl rings are 2.13 (9) and 2.19 (9)&a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813001062 |
| _version_ | 1818998511939616768 |
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| author | Thothadri Srinivasan Panneerselvam Yuvaraj Boreddy S. R. Reddy Devadasan Velmurugan |
| author_facet | Thothadri Srinivasan Panneerselvam Yuvaraj Boreddy S. R. Reddy Devadasan Velmurugan |
| author_sort | Thothadri Srinivasan |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C18H14ClNO3, contains two independent molecules (A and B). In both molecules, the cyclohexanone ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chlorophenyl rings are 2.13 (9) and 2.19 (9)°, respectively, in A, and 0.82 (9) and 1.93 (9)°, respectively, in B. The carbonyl O atoms deviate from the pyran and benzene rings to which they are attached by −0.092 (2) and 0.064 (2) Å, respectively, in A, and by −0.080 (2) and −0.063 (2) Å, respectively, in B. In the crystal, the A molecules are linked via C—H...O hydrogen bonds, forming double-stranded chains along [100]. They lie parallel to the double-stranded chains formed by the B molecules, which are also linked via C—H...O hydrogen bonds. The chains stack up the c axis in an –A–A–B–B–A–A– manner, with a number of π–π interactions involving A and B molecules; the centroid–centroid distances vary from 3.4862 (11) to 3.6848 (11) Å |
| first_indexed | 2024-12-20T22:02:42Z |
| format | Article |
| id | doaj.art-a471ee2361aa435dafd00989a70e5e48 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:02:42Z |
| publishDate | 2013-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a471ee2361aa435dafd00989a70e5e482022-12-21T19:25:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692o253o25310.1107/S16005368130010622-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dioneThothadri SrinivasanPanneerselvam YuvarajBoreddy S. R. ReddyDevadasan VelmuruganThe asymmetric unit of the title compound, C18H14ClNO3, contains two independent molecules (A and B). In both molecules, the cyclohexanone ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chlorophenyl rings are 2.13 (9) and 2.19 (9)°, respectively, in A, and 0.82 (9) and 1.93 (9)°, respectively, in B. The carbonyl O atoms deviate from the pyran and benzene rings to which they are attached by −0.092 (2) and 0.064 (2) Å, respectively, in A, and by −0.080 (2) and −0.063 (2) Å, respectively, in B. In the crystal, the A molecules are linked via C—H...O hydrogen bonds, forming double-stranded chains along [100]. They lie parallel to the double-stranded chains formed by the B molecules, which are also linked via C—H...O hydrogen bonds. The chains stack up the c axis in an –A–A–B–B–A–A– manner, with a number of π–π interactions involving A and B molecules; the centroid–centroid distances vary from 3.4862 (11) to 3.6848 (11) Åhttp://scripts.iucr.org/cgi-bin/paper?S1600536813001062 |
| spellingShingle | Thothadri Srinivasan Panneerselvam Yuvaraj Boreddy S. R. Reddy Devadasan Velmurugan 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione Acta Crystallographica Section E |
| title | 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione |
| title_full | 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione |
| title_fullStr | 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione |
| title_full_unstemmed | 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione |
| title_short | 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione |
| title_sort | 2 chloro 8 8 dimethyl 8 9 dihydro 7h chromeno 2 3 b quinoline 10 12 dione |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813001062 |
| work_keys_str_mv | AT thothadrisrinivasan 2chloro88dimethyl89dihydro7hchromeno23bquinoline1012dione AT panneerselvamyuvaraj 2chloro88dimethyl89dihydro7hchromeno23bquinoline1012dione AT boreddysrreddy 2chloro88dimethyl89dihydro7hchromeno23bquinoline1012dione AT devadasanvelmurugan 2chloro88dimethyl89dihydro7hchromeno23bquinoline1012dione |