Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility

Humidity sensors are indispensable for various electronic systems and instrumentations. To develop a new humidity sensing mechanism is the key for the next generation of sensor technology. In this work, a novel flexible paper-based current humidity sensor is proposed. The developed alternating curre...

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Main Authors: Yaqin He, Mengyao Zhang, Nan Zhang, Danrong Zhu, Chun Huang, Ling Kang, Xiaofeng Zhou, Menghan Hu, Jian Zhang
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/19/21/4607
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author Yaqin He
Mengyao Zhang
Nan Zhang
Danrong Zhu
Chun Huang
Ling Kang
Xiaofeng Zhou
Menghan Hu
Jian Zhang
author_facet Yaqin He
Mengyao Zhang
Nan Zhang
Danrong Zhu
Chun Huang
Ling Kang
Xiaofeng Zhou
Menghan Hu
Jian Zhang
author_sort Yaqin He
collection DOAJ
description Humidity sensors are indispensable for various electronic systems and instrumentations. To develop a new humidity sensing mechanism is the key for the next generation of sensor technology. In this work, a novel flexible paper-based current humidity sensor is proposed. The developed alternating current electroluminescent devices (ACEL) consist of the electroless plating Ni on filter paper and silver nanowires (AgNWs) as the bottom and upper electrodes, and ZnS:Cu as the phosphor layer, respectively. The proposed humidity sensor is based on ACEL with the paper substrate and the ZnS:Cu phosphor layer as the humidity sensing element. The moisture effect on the optical properties of ACELs has been studied firstly. Then, the processing parameters of the paper-based ACELs such as electroless plated bottom electrode and spin-coated phosphor layer as a function of the humidity-sensitive characteristics are investigated. The sensing mechanism of the proposed sensor has been elucidated based on the <inline-formula> <math display="inline"> <semantics> <mrow> <mi>Q</mi> <mo>~</mo> <mi>V</mi> </mrow> </semantics> </math> </inline-formula> analysis. The sensor exhibits an excellent linearity (<inline-formula> <math display="inline"> <semantics> <mrow> <msup> <mi>R</mi> <mn>2</mn> </msup> <mo>=</mo> <mn>0.99965</mn> </mrow> </semantics> </math> </inline-formula>) within the humidity range from 20% to 90% relative humidity (RH) and shows excellent flexibility. We also demonstrate its potential application in postharvest preservation where the EL light is used for preservation and the humidity can be monitored simultaneously through the current.
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spelling doaj.art-a482a536451a4ed2a7d37c53e66ff6792022-12-22T02:57:00ZengMDPI AGSensors1424-82202019-10-011921460710.3390/s19214607s19214607Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and FlexibilityYaqin He0Mengyao Zhang1Nan Zhang2Danrong Zhu3Chun Huang4Ling Kang5Xiaofeng Zhou6Menghan Hu7Jian Zhang8Shanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaShanghai Key Laboratory of Multidimensional Information Processing, East China Normal University, 500 Dongchuan Road, Shanghai 200241, ChinaHumidity sensors are indispensable for various electronic systems and instrumentations. To develop a new humidity sensing mechanism is the key for the next generation of sensor technology. In this work, a novel flexible paper-based current humidity sensor is proposed. The developed alternating current electroluminescent devices (ACEL) consist of the electroless plating Ni on filter paper and silver nanowires (AgNWs) as the bottom and upper electrodes, and ZnS:Cu as the phosphor layer, respectively. The proposed humidity sensor is based on ACEL with the paper substrate and the ZnS:Cu phosphor layer as the humidity sensing element. The moisture effect on the optical properties of ACELs has been studied firstly. Then, the processing parameters of the paper-based ACELs such as electroless plated bottom electrode and spin-coated phosphor layer as a function of the humidity-sensitive characteristics are investigated. The sensing mechanism of the proposed sensor has been elucidated based on the <inline-formula> <math display="inline"> <semantics> <mrow> <mi>Q</mi> <mo>~</mo> <mi>V</mi> </mrow> </semantics> </math> </inline-formula> analysis. The sensor exhibits an excellent linearity (<inline-formula> <math display="inline"> <semantics> <mrow> <msup> <mi>R</mi> <mn>2</mn> </msup> <mo>=</mo> <mn>0.99965</mn> </mrow> </semantics> </math> </inline-formula>) within the humidity range from 20% to 90% relative humidity (RH) and shows excellent flexibility. We also demonstrate its potential application in postharvest preservation where the EL light is used for preservation and the humidity can be monitored simultaneously through the current.https://www.mdpi.com/1424-8220/19/21/4607paper-based acelcapacitive humidity sensorzns:cuflexiblehigh–linearity
spellingShingle Yaqin He
Mengyao Zhang
Nan Zhang
Danrong Zhu
Chun Huang
Ling Kang
Xiaofeng Zhou
Menghan Hu
Jian Zhang
Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
Sensors
paper-based acel
capacitive humidity sensor
zns:cu
flexible
high–linearity
title Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
title_full Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
title_fullStr Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
title_full_unstemmed Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
title_short Paper-Based ZnS:Cu Alternating Current Electroluminescent Devices for Current Humidity Sensors with High–Linearity and Flexibility
title_sort paper based zns cu alternating current electroluminescent devices for current humidity sensors with high linearity and flexibility
topic paper-based acel
capacitive humidity sensor
zns:cu
flexible
high–linearity
url https://www.mdpi.com/1424-8220/19/21/4607
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