Construção artesanal de um eletrodo íon seletivo a chumbo(II): uma alternativa para disciplinas experimentais Homemade construction of a lead(II) ion selective electrode: an alternative to experimental subjects

<abstract language="eng">This works proposes a homemade construction of a lead(II) ISE of solid membrane (Ag2S/PbS) to determine Pb2+ ions in potentiometric titrations, using damaged combined glass electrodes. This electrode can be constructed in teaching laboratories, using it as a...

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Bibliographic Details
Main Authors: Jonatas Gomes da Silva, Arilson Lehmkuhl, Silvia Keli de Barros Alcanfor
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2009-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000400039
Description
Summary:<abstract language="eng">This works proposes a homemade construction of a lead(II) ISE of solid membrane (Ag2S/PbS) to determine Pb2+ ions in potentiometric titrations, using damaged combined glass electrodes. This electrode can be constructed in teaching laboratories, using it as a learning tool related to the theoretical principle of ISE. The analytical curve obtained (y = 27.056x + 337.58; R = 0.996) was linear on the range of 1 x 10-5 to 1 mol L-1 and has presented a very close behavior of the Nernstian. The homemade ISE has presented a similar selectivity to the commercial electrodes, showing to be a good alternative to the experimental activities on teaching laboratories.
ISSN:0100-4042
1678-7064