Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions
A method for determining the critical values of the flow speed and the flow constriction degree characteristic of the alignment of cylindrical nano-objects in a flowing suspension is proposed. Previously, the alignment process of cylindrical nano-objects in suspensions was investigated by using bire...
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| Format: | Article |
| Language: | English |
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Elsevier
2017-01-01
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| Series: | MethodsX |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2215016117300328 |
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| author | Alexander A. Loshkarev Maria F. Vlasova Natalya I. Sapronova Yuri M. Tokunov Ivan A. Volkov Victor V. Ivanov Thomas Maeder |
| author_facet | Alexander A. Loshkarev Maria F. Vlasova Natalya I. Sapronova Yuri M. Tokunov Ivan A. Volkov Victor V. Ivanov Thomas Maeder |
| author_sort | Alexander A. Loshkarev |
| collection | DOAJ |
| description | A method for determining the critical values of the flow speed and the flow constriction degree characteristic of the alignment of cylindrical nano-objects in a flowing suspension is proposed. Previously, the alignment process of cylindrical nano-objects in suspensions was investigated by using birefringence of the polarized light and the small-angle X-ray scattering. While both methods are suitable for measuring the alignment degree of cylindrical nano-objects in suspensions diluted down to low concentrations, they are restricted for the application to undiluted concentrated suspensions because of non-transparency and multiple scattering of X-rays. In addition, the use of the second method requires an expensive synchrotron equipment. We present a simple and faster method based on the direct ultrasound attenuation measurements of longitudinal viscosity of a suspension containing cylindrical nano-objects, which decreases monotonically, approaching its asymptotic value with increase in the flow speed and the flow constriction degree. The principle and advantages of the proposed method are as follows:
• The cylindrical nano-objects align along an accelerated flow at overcritical values of the flow speed and the constriction degree.
• The critical values correspond to the state of a suspension possessing viscosity close to the asymptotic value.
• The method is applicable to undiluted concentrated suspensions, including opaque ones. |
| first_indexed | 2024-12-11T01:57:31Z |
| format | Article |
| id | doaj.art-a4facdd0ce534a6f81eb5ed50f50efbb |
| institution | Directory Open Access Journal |
| issn | 2215-0161 |
| language | English |
| last_indexed | 2024-12-11T01:57:31Z |
| publishDate | 2017-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | MethodsX |
| spelling | doaj.art-a4facdd0ce534a6f81eb5ed50f50efbb2022-12-22T01:24:35ZengElsevierMethodsX2215-01612017-01-014C30530910.1016/j.mex.2017.09.002Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensionsAlexander A. Loshkarev0Maria F. Vlasova1Natalya I. Sapronova2Yuri M. Tokunov3Ivan A. Volkov4Victor V. Ivanov5Thomas Maeder6Moscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaMoscow Institute of Physics and Technology (State University), Institutskii per. 9, Dolgoprudny, Moscow Region 141701, RussiaA method for determining the critical values of the flow speed and the flow constriction degree characteristic of the alignment of cylindrical nano-objects in a flowing suspension is proposed. Previously, the alignment process of cylindrical nano-objects in suspensions was investigated by using birefringence of the polarized light and the small-angle X-ray scattering. While both methods are suitable for measuring the alignment degree of cylindrical nano-objects in suspensions diluted down to low concentrations, they are restricted for the application to undiluted concentrated suspensions because of non-transparency and multiple scattering of X-rays. In addition, the use of the second method requires an expensive synchrotron equipment. We present a simple and faster method based on the direct ultrasound attenuation measurements of longitudinal viscosity of a suspension containing cylindrical nano-objects, which decreases monotonically, approaching its asymptotic value with increase in the flow speed and the flow constriction degree. The principle and advantages of the proposed method are as follows: • The cylindrical nano-objects align along an accelerated flow at overcritical values of the flow speed and the constriction degree. • The critical values correspond to the state of a suspension possessing viscosity close to the asymptotic value. • The method is applicable to undiluted concentrated suspensions, including opaque ones.http://www.sciencedirect.com/science/article/pii/S2215016117300328Ultrasound attenuationLongitudinal viscositySuspensionCylindrical nano-objectsAlignmentCritical parameters |
| spellingShingle | Alexander A. Loshkarev Maria F. Vlasova Natalya I. Sapronova Yuri M. Tokunov Ivan A. Volkov Victor V. Ivanov Thomas Maeder Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions MethodsX Ultrasound attenuation Longitudinal viscosity Suspension Cylindrical nano-objects Alignment Critical parameters |
| title | Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions |
| title_full | Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions |
| title_fullStr | Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions |
| title_full_unstemmed | Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions |
| title_short | Determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano-objects in suspensions |
| title_sort | determination of the critical values of flow parameters characteristic of the alignment of cylindrical nano objects in suspensions |
| topic | Ultrasound attenuation Longitudinal viscosity Suspension Cylindrical nano-objects Alignment Critical parameters |
| url | http://www.sciencedirect.com/science/article/pii/S2215016117300328 |
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