N,N′-Dimethylethylenediammonium dioxalatocuprate(II)
The asymmetric unit of the title salt, (C4H14N2)[Cu(C2O4)2], consists of one complex anion and two cationic half-molecules, the other halves being generated by inversion symmetry. The CuII atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar geometry. Interm...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-08-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025682 |
_version_ | 1818491584257196032 |
---|---|
author | Papa Aly Gaye Aminata Diassé Sarr Mohamed Gaye Morgane Sanselme Peulon Valérie Agasse |
author_facet | Papa Aly Gaye Aminata Diassé Sarr Mohamed Gaye Morgane Sanselme Peulon Valérie Agasse |
author_sort | Papa Aly Gaye |
collection | DOAJ |
description | The asymmetric unit of the title salt, (C4H14N2)[Cu(C2O4)2], consists of one complex anion and two cationic half-molecules, the other halves being generated by inversion symmetry. The CuII atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar geometry. Intermolecular hydrogen bonds, involving the NH groups as donors and O atoms as acceptors, are observed, which lead to the formation of a three-dimensional network structure. |
first_indexed | 2024-12-10T17:32:57Z |
format | Article |
id | doaj.art-a520daf0166847799956ca26b988c3f5 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-10T17:32:57Z |
publishDate | 2011-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-a520daf0166847799956ca26b988c3f52022-12-22T01:39:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1046m104610.1107/S1600536811025682N,N′-Dimethylethylenediammonium dioxalatocuprate(II)Papa Aly GayeAminata Diassé SarrMohamed GayeMorgane SanselmePeulon Valérie AgasseThe asymmetric unit of the title salt, (C4H14N2)[Cu(C2O4)2], consists of one complex anion and two cationic half-molecules, the other halves being generated by inversion symmetry. The CuII atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar geometry. Intermolecular hydrogen bonds, involving the NH groups as donors and O atoms as acceptors, are observed, which lead to the formation of a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811025682 |
spellingShingle | Papa Aly Gaye Aminata Diassé Sarr Mohamed Gaye Morgane Sanselme Peulon Valérie Agasse N,N′-Dimethylethylenediammonium dioxalatocuprate(II) Acta Crystallographica Section E |
title | N,N′-Dimethylethylenediammonium dioxalatocuprate(II) |
title_full | N,N′-Dimethylethylenediammonium dioxalatocuprate(II) |
title_fullStr | N,N′-Dimethylethylenediammonium dioxalatocuprate(II) |
title_full_unstemmed | N,N′-Dimethylethylenediammonium dioxalatocuprate(II) |
title_short | N,N′-Dimethylethylenediammonium dioxalatocuprate(II) |
title_sort | n n amp 8242 dimethylethylenediammonium dioxalatocuprate ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536811025682 |
work_keys_str_mv | AT papaalygaye nnamp8242dimethylethylenediammoniumdioxalatocuprateii AT aminatadiassamp233sarr nnamp8242dimethylethylenediammoniumdioxalatocuprateii AT mohamedgaye nnamp8242dimethylethylenediammoniumdioxalatocuprateii AT morganesanselme nnamp8242dimethylethylenediammoniumdioxalatocuprateii AT peulonvalamp233rieagasse nnamp8242dimethylethylenediammoniumdioxalatocuprateii |