5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran
The title compound, C17H15BrO2S, which was synthesized by the oxidation of 5-bromo-2,4,6-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid, features a trigonally-coordinated S atom. The phenyl ring is approximately perpendicular to the plane of the benzofuran fragment [dihedral...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680802669X |
| _version_ | 1818958953510338560 |
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| author | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| author_facet | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| author_sort | Uk Lee |
| collection | DOAJ |
| description | The title compound, C17H15BrO2S, which was synthesized by the oxidation of 5-bromo-2,4,6-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid, features a trigonally-coordinated S atom. The phenyl ring is approximately perpendicular to the plane of the benzofuran fragment [dihedral angle 75.11 (7)°]. The crystal structure is stabilized by non-classical C—H...O and Br...Br interactions [3.7169 (6) Å]. |
| first_indexed | 2024-12-20T11:33:56Z |
| format | Article |
| id | doaj.art-a545858c7e224bbd84111816d5417751 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:33:56Z |
| publishDate | 2008-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a545858c7e224bbd84111816d54177512022-12-21T19:42:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649o1826o182610.1107/S160053680802669X5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuranUk LeeByeng Wha SonPil Ja SeoHong Dae ChoiThe title compound, C17H15BrO2S, which was synthesized by the oxidation of 5-bromo-2,4,6-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid, features a trigonally-coordinated S atom. The phenyl ring is approximately perpendicular to the plane of the benzofuran fragment [dihedral angle 75.11 (7)°]. The crystal structure is stabilized by non-classical C—H...O and Br...Br interactions [3.7169 (6) Å].http://scripts.iucr.org/cgi-bin/paper?S160053680802669X |
| spellingShingle | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran Acta Crystallographica Section E |
| title | 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran |
| title_full | 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran |
| title_fullStr | 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran |
| title_full_unstemmed | 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran |
| title_short | 5-Bromo-2,4,6-trimethyl-3-phenylsulfinyl-1-benzofuran |
| title_sort | 5 bromo 2 4 6 trimethyl 3 phenylsulfinyl 1 benzofuran |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680802669X |
| work_keys_str_mv | AT uklee 5bromo246trimethyl3phenylsulfinyl1benzofuran AT byengwhason 5bromo246trimethyl3phenylsulfinyl1benzofuran AT piljaseo 5bromo246trimethyl3phenylsulfinyl1benzofuran AT hongdaechoi 5bromo246trimethyl3phenylsulfinyl1benzofuran |