Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements

The mechanical properties of energetic crystals (ECs) are relevant to the safety and performance of ammunitions and propellants. Several experimental and theoretical investigations have been conducted on different ECs to study their mechanical properties and effects on sensitivity and stability. Usi...

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Main Authors: Justin Darku Quansah, Xuexue Zhang, Qazi Wasiullah, Qilong Yan
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2023-09-01
Series:FirePhysChem
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2667134422000530
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author Justin Darku Quansah
Xuexue Zhang
Qazi Wasiullah
Qilong Yan
author_facet Justin Darku Quansah
Xuexue Zhang
Qazi Wasiullah
Qilong Yan
author_sort Justin Darku Quansah
collection DOAJ
description The mechanical properties of energetic crystals (ECs) are relevant to the safety and performance of ammunitions and propellants. Several experimental and theoretical investigations have been conducted on different ECs to study their mechanical properties and effects on sensitivity and stability. Using evaluation methods such as nanoindentation, Raman spectroscopy, and molecular dynamic simulations, a significant amount of helpful information on this topic has emerged, some of which are summarized herein. The overall safety and performance of energetic materials depend on the properties of the energetic crystalline ingredients. Properties such as the thermostability and sensitivity of such crystals have been greatly improved using methods such as cocrystallization, recrystallization, coating, and intercalation. The overall strength and, thus, the safety of formulations largely depend on the quality and mechanical strength of included ECs. Therefore, it is essential to investigate the mechanical strengths of the modified ECs. This review also summarizes various theoretical and experimental methods to study the mechanical properties of pure ECs. As a proposal, additional research on the mechanical strength of modified hybrid ECs with improved energy density and sensitivity is necessary to ascribe the inherent mechanisms.
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spelling doaj.art-a553c2a090334ff6b55c8f808754bd6e2023-08-06T04:38:31ZengKeAi Communications Co. Ltd.FirePhysChem2667-13442023-09-0133234254Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievementsJustin Darku Quansah0Xuexue Zhang1Qazi Wasiullah2Qilong Yan3Science and Technology on Combustion, Internal Flow and Thermostructure Laboratory, Northwestern Polytechnical University, Xi'an 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermostructure Laboratory, Northwestern Polytechnical University, Xi'an 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermostructure Laboratory, Northwestern Polytechnical University, Xi'an 710072, ChinaCorresponding author.; Science and Technology on Combustion, Internal Flow and Thermostructure Laboratory, Northwestern Polytechnical University, Xi'an 710072, ChinaThe mechanical properties of energetic crystals (ECs) are relevant to the safety and performance of ammunitions and propellants. Several experimental and theoretical investigations have been conducted on different ECs to study their mechanical properties and effects on sensitivity and stability. Using evaluation methods such as nanoindentation, Raman spectroscopy, and molecular dynamic simulations, a significant amount of helpful information on this topic has emerged, some of which are summarized herein. The overall safety and performance of energetic materials depend on the properties of the energetic crystalline ingredients. Properties such as the thermostability and sensitivity of such crystals have been greatly improved using methods such as cocrystallization, recrystallization, coating, and intercalation. The overall strength and, thus, the safety of formulations largely depend on the quality and mechanical strength of included ECs. Therefore, it is essential to investigate the mechanical strengths of the modified ECs. This review also summarizes various theoretical and experimental methods to study the mechanical properties of pure ECs. As a proposal, additional research on the mechanical strength of modified hybrid ECs with improved energy density and sensitivity is necessary to ascribe the inherent mechanisms.http://www.sciencedirect.com/science/article/pii/S2667134422000530Energetic crystalsMechanical propertiesThermophysical propertiesMD simulationsNanoindentation
spellingShingle Justin Darku Quansah
Xuexue Zhang
Qazi Wasiullah
Qilong Yan
Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
FirePhysChem
Energetic crystals
Mechanical properties
Thermophysical properties
MD simulations
Nanoindentation
title Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
title_full Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
title_fullStr Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
title_full_unstemmed Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
title_short Mechanical and thermophysical properties of energetic crystals: evaluation methods and recent achievements
title_sort mechanical and thermophysical properties of energetic crystals evaluation methods and recent achievements
topic Energetic crystals
Mechanical properties
Thermophysical properties
MD simulations
Nanoindentation
url http://www.sciencedirect.com/science/article/pii/S2667134422000530
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AT xuexuezhang mechanicalandthermophysicalpropertiesofenergeticcrystalsevaluationmethodsandrecentachievements
AT qaziwasiullah mechanicalandthermophysicalpropertiesofenergeticcrystalsevaluationmethodsandrecentachievements
AT qilongyan mechanicalandthermophysicalpropertiesofenergeticcrystalsevaluationmethodsandrecentachievements