Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators

Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolyme...

Full description

Bibliographic Details
Main Authors: Deepalekshmi Ponnamma, Mariem Mohammed Chamakh, Abdulrhman Mohmmed Alahzm, Nisa Salim, Nishar Hameed, Mariam Al Ali AlMaadeed
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/10/2344
_version_ 1797551154532450304
author Deepalekshmi Ponnamma
Mariem Mohammed Chamakh
Abdulrhman Mohmmed Alahzm
Nisa Salim
Nishar Hameed
Mariam Al Ali AlMaadeed
author_facet Deepalekshmi Ponnamma
Mariem Mohammed Chamakh
Abdulrhman Mohmmed Alahzm
Nisa Salim
Nishar Hameed
Mariam Al Ali AlMaadeed
author_sort Deepalekshmi Ponnamma
collection DOAJ
description Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO<sub>2</sub> and ZnO. The nanotubes of TiO<sub>2</sub> and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics.
first_indexed 2024-03-10T15:40:41Z
format Article
id doaj.art-a5667d29542d47a9aa72bc9f48a8b64b
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-10T15:40:41Z
publishDate 2020-10-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-a5667d29542d47a9aa72bc9f48a8b64b2023-11-20T16:53:54ZengMDPI AGPolymers2073-43602020-10-011210234410.3390/polym12102344Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric NanogeneratorsDeepalekshmi Ponnamma0Mariem Mohammed Chamakh1Abdulrhman Mohmmed Alahzm2Nisa Salim3Nishar Hameed4Mariam Al Ali AlMaadeed5Center for Advanced Materials, Qatar University, Doha P.O. Box 2713, QatarCenter for Advanced Materials, Qatar University, Doha P.O. Box 2713, QatarDepartment of Chemistry and Earth Sciences, College of Arts and Science, Qatar University, Doha P.O. Box 2713, QatarFaculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Melbourne, VIC 3122, AustraliaFaculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Melbourne, VIC 3122, AustraliaMaterials Science & Technology Program (MATS), College of Arts & Sciences, Qatar University, Doha 2713, QatarFlexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO<sub>2</sub> and ZnO. The nanotubes of TiO<sub>2</sub> and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics.https://www.mdpi.com/2073-4360/12/10/2344coaxial spinningnanogeneratorsemiconducting nanoparticleshydrothermal synthesis
spellingShingle Deepalekshmi Ponnamma
Mariem Mohammed Chamakh
Abdulrhman Mohmmed Alahzm
Nisa Salim
Nishar Hameed
Mariam Al Ali AlMaadeed
Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
Polymers
coaxial spinning
nanogenerator
semiconducting nanoparticles
hydrothermal synthesis
title Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
title_full Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
title_fullStr Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
title_full_unstemmed Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
title_short Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
title_sort core shell nanofibers of polyvinylidene fluoride based nanocomposites as piezoelectric nanogenerators
topic coaxial spinning
nanogenerator
semiconducting nanoparticles
hydrothermal synthesis
url https://www.mdpi.com/2073-4360/12/10/2344
work_keys_str_mv AT deepalekshmiponnamma coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators
AT mariemmohammedchamakh coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators
AT abdulrhmanmohmmedalahzm coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators
AT nisasalim coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators
AT nisharhameed coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators
AT mariamalalialmaadeed coreshellnanofibersofpolyvinylidenefluoridebasednanocompositesaspiezoelectricnanogenerators