Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators
Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolyme...
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MDPI AG
2020-10-01
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Series: | Polymers |
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Online Access: | https://www.mdpi.com/2073-4360/12/10/2344 |
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author | Deepalekshmi Ponnamma Mariem Mohammed Chamakh Abdulrhman Mohmmed Alahzm Nisa Salim Nishar Hameed Mariam Al Ali AlMaadeed |
author_facet | Deepalekshmi Ponnamma Mariem Mohammed Chamakh Abdulrhman Mohmmed Alahzm Nisa Salim Nishar Hameed Mariam Al Ali AlMaadeed |
author_sort | Deepalekshmi Ponnamma |
collection | DOAJ |
description | Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO<sub>2</sub> and ZnO. The nanotubes of TiO<sub>2</sub> and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics. |
first_indexed | 2024-03-10T15:40:41Z |
format | Article |
id | doaj.art-a5667d29542d47a9aa72bc9f48a8b64b |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-10T15:40:41Z |
publishDate | 2020-10-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-a5667d29542d47a9aa72bc9f48a8b64b2023-11-20T16:53:54ZengMDPI AGPolymers2073-43602020-10-011210234410.3390/polym12102344Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric NanogeneratorsDeepalekshmi Ponnamma0Mariem Mohammed Chamakh1Abdulrhman Mohmmed Alahzm2Nisa Salim3Nishar Hameed4Mariam Al Ali AlMaadeed5Center for Advanced Materials, Qatar University, Doha P.O. Box 2713, QatarCenter for Advanced Materials, Qatar University, Doha P.O. Box 2713, QatarDepartment of Chemistry and Earth Sciences, College of Arts and Science, Qatar University, Doha P.O. Box 2713, QatarFaculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Melbourne, VIC 3122, AustraliaFaculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Melbourne, VIC 3122, AustraliaMaterials Science & Technology Program (MATS), College of Arts & Sciences, Qatar University, Doha 2713, QatarFlexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO<sub>2</sub> and ZnO. The nanotubes of TiO<sub>2</sub> and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics.https://www.mdpi.com/2073-4360/12/10/2344coaxial spinningnanogeneratorsemiconducting nanoparticleshydrothermal synthesis |
spellingShingle | Deepalekshmi Ponnamma Mariem Mohammed Chamakh Abdulrhman Mohmmed Alahzm Nisa Salim Nishar Hameed Mariam Al Ali AlMaadeed Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators Polymers coaxial spinning nanogenerator semiconducting nanoparticles hydrothermal synthesis |
title | Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators |
title_full | Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators |
title_fullStr | Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators |
title_full_unstemmed | Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators |
title_short | Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators |
title_sort | core shell nanofibers of polyvinylidene fluoride based nanocomposites as piezoelectric nanogenerators |
topic | coaxial spinning nanogenerator semiconducting nanoparticles hydrothermal synthesis |
url | https://www.mdpi.com/2073-4360/12/10/2344 |
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