Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films

PLA films, as non-absorbent materials, require modification of the surface before the printing process in order to improve the wettability of the substrate and to obtain proper ink adhesion to the substrate. In this paper, the surfaces of two kinds of PLA films were modified using plasma activation...

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Main Author: Joanna Izdebska-Podsiadły
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/17/8245
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author Joanna Izdebska-Podsiadły
author_facet Joanna Izdebska-Podsiadły
author_sort Joanna Izdebska-Podsiadły
collection DOAJ
description PLA films, as non-absorbent materials, require modification of the surface before the printing process in order to improve the wettability of the substrate and to obtain proper ink adhesion to the substrate. In this paper, the surfaces of two kinds of PLA films were modified using plasma activation with parameters enabling high surface free energy (SFE) values, and then the films were printed on using different kinds of flexographic inks. Two gases, oxygen and argon, were used for activation, as these make it possible to obtain good hydrophilicity and high SFE values while having different effects on the roughness, or the degree of surface etching. Plasma-activated films were subsequently subjected to the measurements of: contact angle with water, diiodomethane and three printing inks, roughness, weight change, strength properties, color and gloss change, and SFE was determined. Unmodified and activated films were flexographically printed in laboratory conditions and then the quality of obtained prints was analyzed. The results showed a strong effect of activation with both oxygen and argon plasma on the SFE value of the films and the contact angles of water and inks, with the gas used for plasma activation and the type of film significantly influencing the thickness of the fused ink layer and the resultant color. Moreover, plasma activation had a especially favorable and significant effect on the quality of prints made with water-based inks, while it had little effect when printing with solvent-based inks.
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spelling doaj.art-a570063952224649be36be7ee6282ed32023-11-22T10:23:54ZengMDPI AGApplied Sciences2076-34172021-09-011117824510.3390/app11178245Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA FilmsJoanna Izdebska-Podsiadły0Department of Printing Technology, Institute of Mechanics and Printing, Faculty of Mechanical and Industrial Engineering, Warsaw University of Technology, Konwiktorska 2, 00-217 Warsaw, PolandPLA films, as non-absorbent materials, require modification of the surface before the printing process in order to improve the wettability of the substrate and to obtain proper ink adhesion to the substrate. In this paper, the surfaces of two kinds of PLA films were modified using plasma activation with parameters enabling high surface free energy (SFE) values, and then the films were printed on using different kinds of flexographic inks. Two gases, oxygen and argon, were used for activation, as these make it possible to obtain good hydrophilicity and high SFE values while having different effects on the roughness, or the degree of surface etching. Plasma-activated films were subsequently subjected to the measurements of: contact angle with water, diiodomethane and three printing inks, roughness, weight change, strength properties, color and gloss change, and SFE was determined. Unmodified and activated films were flexographically printed in laboratory conditions and then the quality of obtained prints was analyzed. The results showed a strong effect of activation with both oxygen and argon plasma on the SFE value of the films and the contact angles of water and inks, with the gas used for plasma activation and the type of film significantly influencing the thickness of the fused ink layer and the resultant color. Moreover, plasma activation had a especially favorable and significant effect on the quality of prints made with water-based inks, while it had little effect when printing with solvent-based inks.https://www.mdpi.com/2076-3417/11/17/8245plasma activationPLA filmsbiodegradable polymerswater-based inkssolvent-based inksflexographic printing
spellingShingle Joanna Izdebska-Podsiadły
Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
Applied Sciences
plasma activation
PLA films
biodegradable polymers
water-based inks
solvent-based inks
flexographic printing
title Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
title_full Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
title_fullStr Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
title_full_unstemmed Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
title_short Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films
title_sort effect of plasma surface modification on print quality of biodegradable pla films
topic plasma activation
PLA films
biodegradable polymers
water-based inks
solvent-based inks
flexographic printing
url https://www.mdpi.com/2076-3417/11/17/8245
work_keys_str_mv AT joannaizdebskapodsiadły effectofplasmasurfacemodificationonprintqualityofbiodegradableplafilms