Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate

"Millable polyurethane rubber (MPU)/ poly(dodecalactam) (PA 12) thermoplastic vulcanizate (TPV) was prepared via dynamic vulcanization method, and the dynamic vulcanization process of MPU/PA 12 TPV was explored by controlling the dynamic vulcanization time, At the same time, physical and mecha...

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Main Author: HAN Xiao1,2,DONG Xiao-kun2,DENG Tao2
Format: Article
Language:zho
Published: Editorial Office of China Synthetic Rubber Industry 2022-06-01
Series:Hecheng xiangjiao gongye
Subjects:
Online Access:http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202206011
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author HAN Xiao1,2,DONG Xiao-kun2,DENG Tao2
author_facet HAN Xiao1,2,DONG Xiao-kun2,DENG Tao2
author_sort HAN Xiao1,2,DONG Xiao-kun2,DENG Tao2
collection DOAJ
description "Millable polyurethane rubber (MPU)/ poly(dodecalactam) (PA 12) thermoplastic vulcanizate (TPV) was prepared via dynamic vulcanization method, and the dynamic vulcanization process of MPU/PA 12 TPV was explored by controlling the dynamic vulcanization time, At the same time, physical and mechanical properties, and dynamical mechanical properties of the blends in different dynamic vulcanization stage were studied. The results showed that with the extension of dynamic vulca-nization time, MPU/PA 12 TPV gradually completed the phase transformation process. Under the action of temperature and shear force, MPU phase changed from continuous phase to dispersed phase, while PA 12 phase changed from dispersed phase to conti-nuous phase. Storage modulus of MPU/PA 12 blends increased, loss modulus decreased, and loss factor reduced with the extension of dynamic vulcanization time. In addition, the comprehensive mechanical properties of MPU/PA 12 blends were improved with the extension of dynamic vulcanization time."
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spelling doaj.art-a57e3dc7230e4471b0a0f99995ae48c42022-12-27T03:24:50ZzhoEditorial Office of China Synthetic Rubber IndustryHecheng xiangjiao gongye1000-12552022-06-0145650551010.19908/j.cnki.ISSN1000-1255.2022.06.0505Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizateHAN Xiao1,2,DONG Xiao-kun2,DENG Tao201. Luoyang Ship Material Research Institute, Luoyang 471023, China; 2. School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China"Millable polyurethane rubber (MPU)/ poly(dodecalactam) (PA 12) thermoplastic vulcanizate (TPV) was prepared via dynamic vulcanization method, and the dynamic vulcanization process of MPU/PA 12 TPV was explored by controlling the dynamic vulcanization time, At the same time, physical and mechanical properties, and dynamical mechanical properties of the blends in different dynamic vulcanization stage were studied. The results showed that with the extension of dynamic vulca-nization time, MPU/PA 12 TPV gradually completed the phase transformation process. Under the action of temperature and shear force, MPU phase changed from continuous phase to dispersed phase, while PA 12 phase changed from dispersed phase to conti-nuous phase. Storage modulus of MPU/PA 12 blends increased, loss modulus decreased, and loss factor reduced with the extension of dynamic vulcanization time. In addition, the comprehensive mechanical properties of MPU/PA 12 blends were improved with the extension of dynamic vulcanization time." http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202206011millable polyurethane rubberpolydodecalactamdynamic vulcanizationthermoplastic vulcanizateblendcuring characteristicmechanical property
spellingShingle HAN Xiao1,2,DONG Xiao-kun2,DENG Tao2
Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
Hecheng xiangjiao gongye
millable polyurethane rubber
polydodecalactam
dynamic vulcanization
thermoplastic vulcanizate
blend
curing characteristic
mechanical property
title Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
title_full Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
title_fullStr Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
title_full_unstemmed Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
title_short Dynamic vulcanization process and properties of millable polyurethane rubber/polylaurolactam thermoplastic vulcanizate
title_sort dynamic vulcanization process and properties of millable polyurethane rubber polylaurolactam thermoplastic vulcanizate
topic millable polyurethane rubber
polydodecalactam
dynamic vulcanization
thermoplastic vulcanizate
blend
curing characteristic
mechanical property
url http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202206011
work_keys_str_mv AT hanxiao12dongxiaokun2dengtao2 dynamicvulcanizationprocessandpropertiesofmillablepolyurethanerubberpolylaurolactamthermoplasticvulcanizate