RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers

Abstract In this work, we propose a method to improve electro-optical and structural parameters of light-absorbing kesterite materials. It relies on the application of weak power hydrogen plasma discharges using electromagnetic field of radio frequency range, which improves homogeneity of the sample...

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Main Authors: Mykola O. Semenenko, Ivan S. Babichuk, Oleksandr Kyriienko, Ivan V. Bodnar, Raquel Caballero, Maximo Leon
Format: Article
Language:English
Published: SpringerOpen 2017-06-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-017-2183-9
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author Mykola O. Semenenko
Ivan S. Babichuk
Oleksandr Kyriienko
Ivan V. Bodnar
Raquel Caballero
Maximo Leon
author_facet Mykola O. Semenenko
Ivan S. Babichuk
Oleksandr Kyriienko
Ivan V. Bodnar
Raquel Caballero
Maximo Leon
author_sort Mykola O. Semenenko
collection DOAJ
description Abstract In this work, we propose a method to improve electro-optical and structural parameters of light-absorbing kesterite materials. It relies on the application of weak power hydrogen plasma discharges using electromagnetic field of radio frequency range, which improves homogeneity of the samples. The method allows to reduce strain of light absorbers and is suitable for designing solar cells based on multilayered thin film structures. Structural characteristics of tetragonal kesterite Cu2ZnSn(S, Se)4 structures and their optical properties were studied by Raman, infrared, and reflectance spectroscopies. They revealed a reduction of the sample reflectivity after RF treatment and a modification of the energy band structure.
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spelling doaj.art-a5874b2fe33742d68d3fd7d226e697772023-08-02T01:34:55ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-06-011211810.1186/s11671-017-2183-9RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light AbsorbersMykola O. Semenenko0Ivan S. Babichuk1Oleksandr Kyriienko2Ivan V. Bodnar3Raquel Caballero4Maximo Leon5V.Ye. Lashkaryov Institute of Semiconductor Physics, National Academy of Sciences of UkraineV.Ye. Lashkaryov Institute of Semiconductor Physics, National Academy of Sciences of UkraineThe Niels Bohr Institute, University of CopenhagenBelarussky Gosudarstvenniy Universitet Informatiki i Radioelektroniki – BSU-BEPhotovoltaic Materials Group, Applied Physics Department, University Autonoma of MadridPhotovoltaic Materials Group, Applied Physics Department, University Autonoma of MadridAbstract In this work, we propose a method to improve electro-optical and structural parameters of light-absorbing kesterite materials. It relies on the application of weak power hydrogen plasma discharges using electromagnetic field of radio frequency range, which improves homogeneity of the samples. The method allows to reduce strain of light absorbers and is suitable for designing solar cells based on multilayered thin film structures. Structural characteristics of tetragonal kesterite Cu2ZnSn(S, Se)4 structures and their optical properties were studied by Raman, infrared, and reflectance spectroscopies. They revealed a reduction of the sample reflectivity after RF treatment and a modification of the energy band structure.http://link.springer.com/article/10.1186/s11671-017-2183-9Tetragonal kesteriteLight absorberRadio frequency treatmentPlasma etchingKesterite FTIR investigationRaman spectroscopy
spellingShingle Mykola O. Semenenko
Ivan S. Babichuk
Oleksandr Kyriienko
Ivan V. Bodnar
Raquel Caballero
Maximo Leon
RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
Nanoscale Research Letters
Tetragonal kesterite
Light absorber
Radio frequency treatment
Plasma etching
Kesterite FTIR investigation
Raman spectroscopy
title RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
title_full RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
title_fullStr RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
title_full_unstemmed RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
title_short RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers
title_sort rf electromagnetic field treatment of tetragonal kesterite cztsse light absorbers
topic Tetragonal kesterite
Light absorber
Radio frequency treatment
Plasma etching
Kesterite FTIR investigation
Raman spectroscopy
url http://link.springer.com/article/10.1186/s11671-017-2183-9
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