Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation

The solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressio...

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Main Authors: M.F.Holovko, V.I.Kapko
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2007-09-01
Series:Condensed Matter Physics
Subjects:
Online Access:http://dx.doi.org/10.5488/CMP.10.3.397
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author M.F.Holovko
V.I.Kapko
author_facet M.F.Holovko
V.I.Kapko
author_sort M.F.Holovko
collection DOAJ
description The solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic quantities are represented in a simpler form.Numerical results for thermodynamic properties and phase equilibria are presented.
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spelling doaj.art-a58a7aa749f342d5ba5f518cab9ecd1a2022-12-22T00:54:47ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2007-09-01103397Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximationM.F.HolovkoV.I.KapkoThe solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic quantities are represented in a simpler form.Numerical results for thermodynamic properties and phase equilibria are presented.http://dx.doi.org/10.5488/CMP.10.3.397electrolyte solutionsion-dipole modelassociationAMSAthermodynamicphase equilibrium.
spellingShingle M.F.Holovko
V.I.Kapko
Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
Condensed Matter Physics
electrolyte solutions
ion-dipole model
association
AMSA
thermodynamic
phase equilibrium.
title Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
title_full Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
title_fullStr Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
title_full_unstemmed Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
title_short Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
title_sort ion dipole model for electrolyte solutions application of the associative mean spherical approximation
topic electrolyte solutions
ion-dipole model
association
AMSA
thermodynamic
phase equilibrium.
url http://dx.doi.org/10.5488/CMP.10.3.397
work_keys_str_mv AT mfholovko iondipolemodelforelectrolytesolutionsapplicationoftheassociativemeansphericalapproximation
AT vikapko iondipolemodelforelectrolytesolutionsapplicationoftheassociativemeansphericalapproximation