Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation
The solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressio...
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Format: | Article |
Language: | English |
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Institute for Condensed Matter Physics
2007-09-01
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Series: | Condensed Matter Physics |
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Online Access: | http://dx.doi.org/10.5488/CMP.10.3.397 |
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author | M.F.Holovko V.I.Kapko |
author_facet | M.F.Holovko V.I.Kapko |
author_sort | M.F.Holovko |
collection | DOAJ |
description | The solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic quantities are represented in a simpler form.Numerical results for thermodynamic properties and phase equilibria are presented. |
first_indexed | 2024-12-11T18:35:29Z |
format | Article |
id | doaj.art-a58a7aa749f342d5ba5f518cab9ecd1a |
institution | Directory Open Access Journal |
issn | 1607-324X |
language | English |
last_indexed | 2024-12-11T18:35:29Z |
publishDate | 2007-09-01 |
publisher | Institute for Condensed Matter Physics |
record_format | Article |
series | Condensed Matter Physics |
spelling | doaj.art-a58a7aa749f342d5ba5f518cab9ecd1a2022-12-22T00:54:47ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2007-09-01103397Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximationM.F.HolovkoV.I.KapkoThe solution of the associative mean-spherical approximation for ion-dipolar system is reinvestigated and expressed in terms of only five parameters. Three of them have counterpas in the case without association, and the other two are the monomer fractions of ions and dipoles. The explicit expressions for the thermodynamic quantities are represented in a simpler form.Numerical results for thermodynamic properties and phase equilibria are presented.http://dx.doi.org/10.5488/CMP.10.3.397electrolyte solutionsion-dipole modelassociationAMSAthermodynamicphase equilibrium. |
spellingShingle | M.F.Holovko V.I.Kapko Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation Condensed Matter Physics electrolyte solutions ion-dipole model association AMSA thermodynamic phase equilibrium. |
title | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation |
title_full | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation |
title_fullStr | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation |
title_full_unstemmed | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation |
title_short | Ion-dipole model for electrolyte solutions: Application of the associative mean spherical approximation |
title_sort | ion dipole model for electrolyte solutions application of the associative mean spherical approximation |
topic | electrolyte solutions ion-dipole model association AMSA thermodynamic phase equilibrium. |
url | http://dx.doi.org/10.5488/CMP.10.3.397 |
work_keys_str_mv | AT mfholovko iondipolemodelforelectrolytesolutionsapplicationoftheassociativemeansphericalapproximation AT vikapko iondipolemodelforelectrolytesolutionsapplicationoftheassociativemeansphericalapproximation |