Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)

<p class="orbitalabstract">The identification of cannabinoids directly in seeds is very controversial. According to the Recommended Methods for the Identification and Analysis of Cannabis and Cannabis products, “the seeds themselves do not contain Δ<sup>9</sup>-THC”. It i...

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Main Authors: Nayara A. dos Santos, Rafael S. Ortiz, Renata P. Limberger, Valdemar Lacerda Júnior, Wanderson Romão
Format: Article
Language:English
Published: Universidade Federal de Mato Grosso do Sul 2018-06-01
Series:Orbital: The Electronic Journal of Chemistry
Subjects:
Online Access:http://orbital.ufms.br/index.php/Chemistry/article/view/1149
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author Nayara A. dos Santos
Rafael S. Ortiz
Renata P. Limberger
Valdemar Lacerda Júnior
Wanderson Romão
author_facet Nayara A. dos Santos
Rafael S. Ortiz
Renata P. Limberger
Valdemar Lacerda Júnior
Wanderson Romão
author_sort Nayara A. dos Santos
collection DOAJ
description <p class="orbitalabstract">The identification of cannabinoids directly in seeds is very controversial. According to the Recommended Methods for the Identification and Analysis of Cannabis and Cannabis products, “the seeds themselves do not contain Δ<sup>9</sup>-THC”. It is defended the idea that the detection of Δ<sup>9</sup>-THC when it possibly occurs by contact of the seed with its bracts and/or flowers of the plant, which has a high content of this cannabinoid. In this paper, we reported a simple method of extraction and fast detection of Δ<sup>9</sup>-THC in the internal part of Cannabis seeds by negative-ion mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI(-)FT-ICR MS). Results showed that the method proposed allowed the chemotaxonomic forensic examination to prove the identification of Δ<sup>9</sup>-THC in Cannabis seeds.</p><p class="orbitalabstract"> </p><p class="orbitalabstract">DOI: <a href="http://dx.doi.org/10.17807/orbital.v10i5.1149">http://dx.doi.org/10.17807/orbital.v10i5.1149</a></p><p> </p>
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spelling doaj.art-a58edda5a03e4cf5a4e9b603e2d1d5ad2022-12-21T17:26:39ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282018-06-0110538138510.17807/orbital.v10i5.1149513Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)Nayara A. dos Santos0Rafael S. Ortiz1Renata P. Limberger2Valdemar Lacerda Júnior3Wanderson Romão4Laboratório de Petroleômica e Forense, Universidade Federal do Espírito Santo – Departamento de Química, CEP 29075910, Vitória, Espírito Santo, BrasilSuperintendência da Polícia Federal no Rio Grande do Sul, CEP 90130093, Porto Alegre, Rio Grande do Sul, BrasiFaculdade de Farmácia, Universidade Federal do Rio Grande do Sul, CEP 90610000, Porto Alegre, Rio Grande do Sul, BrasilChemistry Department Federal University of Espirito Santo Vitória, ES, BrazilInstituto Federal do Espírito Santo, IFES – Campus Vila Velha, CEP 29106010, Vila Velha, Espírito Santo Brasil<p class="orbitalabstract">The identification of cannabinoids directly in seeds is very controversial. According to the Recommended Methods for the Identification and Analysis of Cannabis and Cannabis products, “the seeds themselves do not contain Δ<sup>9</sup>-THC”. It is defended the idea that the detection of Δ<sup>9</sup>-THC when it possibly occurs by contact of the seed with its bracts and/or flowers of the plant, which has a high content of this cannabinoid. In this paper, we reported a simple method of extraction and fast detection of Δ<sup>9</sup>-THC in the internal part of Cannabis seeds by negative-ion mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI(-)FT-ICR MS). Results showed that the method proposed allowed the chemotaxonomic forensic examination to prove the identification of Δ<sup>9</sup>-THC in Cannabis seeds.</p><p class="orbitalabstract"> </p><p class="orbitalabstract">DOI: <a href="http://dx.doi.org/10.17807/orbital.v10i5.1149">http://dx.doi.org/10.17807/orbital.v10i5.1149</a></p><p> </p>http://orbital.ufms.br/index.php/Chemistry/article/view/1149cannabis seedsesi(-)ft-icrδ9-tetrahydrocannabinol
spellingShingle Nayara A. dos Santos
Rafael S. Ortiz
Renata P. Limberger
Valdemar Lacerda Júnior
Wanderson Romão
Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
Orbital: The Electronic Journal of Chemistry
cannabis seeds
esi(-)ft-icr
δ9-tetrahydrocannabinol
title Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
title_full Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
title_fullStr Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
title_full_unstemmed Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
title_short Identification of Δ9-Tetrahydrocannabinol (Δ9-THC) in Cannabis seeds by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (ESI(-)FT-ICR MS)
title_sort identification of δ9 tetrahydrocannabinol δ9 thc in cannabis seeds by electrospray ionization fourier transform ion cyclotron resonance mass spectrometry esi ft icr ms
topic cannabis seeds
esi(-)ft-icr
δ9-tetrahydrocannabinol
url http://orbital.ufms.br/index.php/Chemistry/article/view/1149
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