Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture

 To assess the influence of mussel raft systems on several geochemical and sedimentological properties (carbonate and organic matter contents, fractions of Fe and degree of pyritization), six sediment cores were collected from the Ría de Pontevedra area. Four of those cores were collected in mussel...

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Main Authors: I León, G Méndez, B Rubio
Format: Article
Language:English
Published: Universidad Autónoma de Baja California 2004-03-01
Series:Ciencias Marinas
Subjects:
Online Access:https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/340
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author I León
G Méndez
B Rubio
author_facet I León
G Méndez
B Rubio
author_sort I León
collection DOAJ
description  To assess the influence of mussel raft systems on several geochemical and sedimentological properties (carbonate and organic matter contents, fractions of Fe and degree of pyritization), six sediment cores were collected from the Ría de Pontevedra area. Four of those cores were collected in mussel raft areas (biodeposits) and the other two in adjacent areas where mussel rafts do not operate. The degree of pyritization (DOP) varied between 11.89% and 67.30%, with a mean value of 46.36 ± 13.15%. The maximum values of DOP were obtained in sediments from the mussel raft areas, which in turn showed higher values of pyrite Fe, organic matter and mud than the areas without mussel rafts. On the contrary, in the latter areas, coarser sediments with high carbonate content and Fe bound to silicates were the predominant phases. The results show a dominance of more reducing conditions in the biodeposit areas than in the adjacent areas. The DOP values indicate that reactive Fe was not totally converted to pyrite Fe. The significant correlation (r = 0.61) between DOP and organic matter confirmed that the latter is the limiting factor in pyrite genesis. These results allow us to conclude that mussel raft culture significantly changes the sediment texture and geochemical forms of Fe, with the consequent geochemical and environmental implications.
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spelling doaj.art-a5afaa5d13e64db4bb6362f72315632e2024-03-03T18:37:44ZengUniversidad Autónoma de Baja CaliforniaCiencias Marinas0185-38802395-90532004-03-0130410.7773/cm.v30i4.340Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft cultureI León0G Méndez1B Rubio2Universidad del AtlánticoUniversidad de VigoUniversidad de Vigo  To assess the influence of mussel raft systems on several geochemical and sedimentological properties (carbonate and organic matter contents, fractions of Fe and degree of pyritization), six sediment cores were collected from the Ría de Pontevedra area. Four of those cores were collected in mussel raft areas (biodeposits) and the other two in adjacent areas where mussel rafts do not operate. The degree of pyritization (DOP) varied between 11.89% and 67.30%, with a mean value of 46.36 ± 13.15%. The maximum values of DOP were obtained in sediments from the mussel raft areas, which in turn showed higher values of pyrite Fe, organic matter and mud than the areas without mussel rafts. On the contrary, in the latter areas, coarser sediments with high carbonate content and Fe bound to silicates were the predominant phases. The results show a dominance of more reducing conditions in the biodeposit areas than in the adjacent areas. The DOP values indicate that reactive Fe was not totally converted to pyrite Fe. The significant correlation (r = 0.61) between DOP and organic matter confirmed that the latter is the limiting factor in pyrite genesis. These results allow us to conclude that mussel raft culture significantly changes the sediment texture and geochemical forms of Fe, with the consequent geochemical and environmental implications. https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/340degree of pyritizationRía de Pontevedrareactive ironpyrite ironmussel rafts
spellingShingle I León
G Méndez
B Rubio
Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
Ciencias Marinas
degree of pyritization
Ría de Pontevedra
reactive iron
pyrite iron
mussel rafts
title Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
title_full Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
title_fullStr Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
title_full_unstemmed Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
title_short Geochemical phases of Fe and degree of pyritization in sediments from Ría de Pontevedra (NW Spain): Implications of mussel raft culture
title_sort geochemical phases of fe and degree of pyritization in sediments from ria de pontevedra nw spain implications of mussel raft culture
topic degree of pyritization
Ría de Pontevedra
reactive iron
pyrite iron
mussel rafts
url https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/340
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AT gmendez geochemicalphasesoffeanddegreeofpyritizationinsedimentsfromriadepontevedranwspainimplicationsofmusselraftculture
AT brubio geochemicalphasesoffeanddegreeofpyritizationinsedimentsfromriadepontevedranwspainimplicationsofmusselraftculture