Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate
In the title binuclear iron(III) complex, [Fe2(C14H10N2O2)3]·4C4H8O or [Fe2(salda)3]·4THF [H2salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808027438 |
| _version_ | 1818958889418227712 |
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| author | Binsheng Yang Bin Liu Jinglin Wang |
| author_facet | Binsheng Yang Bin Liu Jinglin Wang |
| author_sort | Binsheng Yang |
| collection | DOAJ |
| description | In the title binuclear iron(III) complex, [Fe2(C14H10N2O2)3]·4C4H8O or [Fe2(salda)3]·4THF [H2salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′,O′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic C2 symmetry, the rotation axis bisecting one N—N bond. |
| first_indexed | 2024-12-20T11:32:55Z |
| format | Article |
| id | doaj.art-a5b097a0f16746e28a4d8904716ea0d1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:32:55Z |
| publishDate | 2008-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a5b097a0f16746e28a4d8904716ea0d12022-12-21T19:42:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1210m121010.1107/S1600536808027438Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvateBinsheng YangBin LiuJinglin WangIn the title binuclear iron(III) complex, [Fe2(C14H10N2O2)3]·4C4H8O or [Fe2(salda)3]·4THF [H2salda = 2,2′-(azinidimethylene)diphenolate and THF is tetrahydrofuran], the ligand possesses a rotationally flexible single N—N bond. Three dinucleating O,N:N′,O′-donor ligands provide three diazine (=N—N=) bridges between the metal ions, yielding a binuclear triple helicate structure with crystallographic C2 symmetry, the rotation axis bisecting one N—N bond.http://scripts.iucr.org/cgi-bin/paper?S1600536808027438 |
| spellingShingle | Binsheng Yang Bin Liu Jinglin Wang Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate Acta Crystallographica Section E |
| title | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_full | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_fullStr | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_full_unstemmed | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_short | Tris[μ-2,2′-(azinodimethylidyne)diphenolato-κ4O,N:N′,O′]diiron(III) tetrahydrofuran tetrasolvate |
| title_sort | tris 956 2 2 8242 azinodimethylidyne diphenolato 954 4o n n 8242 o 8242 diiron iii tetrahydrofuran tetrasolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808027438 |
| work_keys_str_mv | AT binshengyang tris956228242azinodimethylidynediphenolato9544onn8242o8242diironiiitetrahydrofurantetrasolvate AT binliu tris956228242azinodimethylidynediphenolato9544onn8242o8242diironiiitetrahydrofurantetrasolvate AT jinglinwang tris956228242azinodimethylidynediphenolato9544onn8242o8242diironiiitetrahydrofurantetrasolvate |