Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate
The title compound, [Cu(C11H15N2O)(C12H8N2)]ClO4 or [Cu(L)(phen)](ClO4) {where L refers to the deprotonated form of 2-[(2-dimethylaminoethylimino)methyl]phenol} and phen is 1,10-phenanthroline) is a mononuclear mixed ligand copper(II) complex. The CuII atom is coordinated by two N and one O atoms of...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023001767 |
| _version_ | 1797851185187651584 |
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| author | Anjaneyulu Mamindla Manikandan Varadhan Marappan Velusamy Venkatasubramanian Ulaganathan Venugopal Rajendiran |
| author_facet | Anjaneyulu Mamindla Manikandan Varadhan Marappan Velusamy Venkatasubramanian Ulaganathan Venugopal Rajendiran |
| author_sort | Anjaneyulu Mamindla |
| collection | DOAJ |
| description | The title compound, [Cu(C11H15N2O)(C12H8N2)]ClO4 or [Cu(L)(phen)](ClO4) {where L refers to the deprotonated form of 2-[(2-dimethylaminoethylimino)methyl]phenol} and phen is 1,10-phenanthroline) is a mononuclear mixed ligand copper(II) complex. The CuII atom is coordinated by two N and one O atoms of the tridentate Schiff base ligand (HL) and two N atoms of the 1,10-phenanthroline ligand, resulting in a five-coordinate complex. The asymmetric unit of the title complex contains two crystallographically independent complex cations (a and b) with a slightly different geometry around the CuII ion. The value of the trigonality index τ, indicates that in both cations a and b, the CuII atoms display a square-pyramidal distorted trigonal–bipyramidal (SPDTBP) geometry, although the distortion is greater for cation a. |
| first_indexed | 2024-04-09T19:13:49Z |
| format | Article |
| id | doaj.art-a5b353fe9fd64a45893fa41c2800c579 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-09T19:13:49Z |
| publishDate | 2023-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-a5b353fe9fd64a45893fa41c2800c5792023-04-06T09:42:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-04-0179425926310.1107/S2056989023001767dj2061Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorateAnjaneyulu Mamindla0Manikandan Varadhan1Marappan Velusamy2Venkatasubramanian Ulaganathan3Venugopal Rajendiran4Department of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur - 610 005, IndiaDepartment of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur - 610 005, IndiaDepartment of Chemistry, North Eastern Hill University, Shillong - 793 022, IndiaSchool of Chemical & Biotechnology, SASTRA Deemed University, Thanjavur - 613 401, Tamil Nadu, IndiaDepartment of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur - 610 005, IndiaThe title compound, [Cu(C11H15N2O)(C12H8N2)]ClO4 or [Cu(L)(phen)](ClO4) {where L refers to the deprotonated form of 2-[(2-dimethylaminoethylimino)methyl]phenol} and phen is 1,10-phenanthroline) is a mononuclear mixed ligand copper(II) complex. The CuII atom is coordinated by two N and one O atoms of the tridentate Schiff base ligand (HL) and two N atoms of the 1,10-phenanthroline ligand, resulting in a five-coordinate complex. The asymmetric unit of the title complex contains two crystallographically independent complex cations (a and b) with a slightly different geometry around the CuII ion. The value of the trigonality index τ, indicates that in both cations a and b, the CuII atoms display a square-pyramidal distorted trigonal–bipyramidal (SPDTBP) geometry, although the distortion is greater for cation a.http://scripts.iucr.org/cgi-bin/paper?S2056989023001767mixed ligand copper(ii) complexesanticancer agentscrystal structuresquare-pyramidal distorted trigonal–bipyramidal (spdtbp) geometry |
| spellingShingle | Anjaneyulu Mamindla Manikandan Varadhan Marappan Velusamy Venkatasubramanian Ulaganathan Venugopal Rajendiran Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate Acta Crystallographica Section E: Crystallographic Communications mixed ligand copper(ii) complexes anticancer agents crystal structure square-pyramidal distorted trigonal–bipyramidal (spdtbp) geometry |
| title | Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_full | Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_fullStr | Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_full_unstemmed | Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_short | Crystal structure of [2-({[2-(dimethylamino-κN)ethyl]imino-κN}methyl)phenolato-κO](1,10-phenanthroline-κ2N,N′)copper(II) perchlorate |
| title_sort | crystal structure of 2 2 dimethylamino κn ethyl imino κn methyl phenolato κo 1 10 phenanthroline κ2n n copper ii perchlorate |
| topic | mixed ligand copper(ii) complexes anticancer agents crystal structure square-pyramidal distorted trigonal–bipyramidal (spdtbp) geometry |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023001767 |
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