Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate
The asymmetric unit of the title complex, [Cu2(C8H4NO6)2Cl2(C10H8N2)2]·2H2O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent CuII cation i...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811046782 |
| _version_ | 1819104977318051840 |
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| author | Hui Wang |
| author_facet | Hui Wang |
| author_sort | Hui Wang |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Cu2(C8H4NO6)2Cl2(C10H8N2)2]·2H2O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent CuII cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ2-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01-1) by O—H...O and O—H...Cl hydrogen bonds. |
| first_indexed | 2024-12-22T02:14:55Z |
| format | Article |
| id | doaj.art-a5b7f5d253224b418260268b2406336c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:14:55Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a5b7f5d253224b418260268b2406336c2022-12-21T18:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m95m9510.1107/S1600536811046782Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrateHui WangThe asymmetric unit of the title complex, [Cu2(C8H4NO6)2Cl2(C10H8N2)2]·2H2O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent CuII cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ2-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01-1) by O—H...O and O—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811046782 |
| spellingShingle | Hui Wang Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate Acta Crystallographica Section E |
| title | Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate |
| title_full | Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate |
| title_fullStr | Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate |
| title_full_unstemmed | Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate |
| title_short | Bis(μ-2-carboxy-5-nitrobenzoato-κ2O1:O1)bis[(2,2′-bipyridine-κ2N:N′)chloridocopper(II)] dihydrate |
| title_sort | bis amp 956 2 carboxy 5 nitrobenzoato amp 954 2o1 o1 bis 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 chloridocopper ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811046782 |
| work_keys_str_mv | AT huiwang bisamp9562carboxy5nitrobenzoatoamp9542o1o1bis22amp8242bipyridineamp9542nnamp8242chloridocopperiidihydrate |