The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)

<p>The Ljubija ore deposits are the loci typici of siderite-barite-polysulphide deposits withinthe Inner Dinarides, Gemerides and Eastern Alps. Numerous sites of ore outcrops, smalleror larger ore bodies of mineralization, consisting of Fe carbonates, sulphides, barite andfluorite are scattere...

Full description

Bibliographic Details
Main Authors: Ladislav Palinkaš, Sibila Borojević Šoštarić, Sabina Strmić Palinkaš, Walter Prochaska, Zoltan Pécskay, Franz Neubauer, Jorge E Spangenberg
Format: Article
Language:English
Published: Croatian Geological Survey 2016-02-01
Series:Geologia Croatica
Subjects:
Online Access:http://www.geologia-croatica.hr/ojs/index.php/GC/article/view/732
_version_ 1819077590835527680
author Ladislav Palinkaš
Sibila Borojević Šoštarić
Sabina Strmić Palinkaš
Walter Prochaska
Zoltan Pécskay
Franz Neubauer
Jorge E Spangenberg
author_facet Ladislav Palinkaš
Sibila Borojević Šoštarić
Sabina Strmić Palinkaš
Walter Prochaska
Zoltan Pécskay
Franz Neubauer
Jorge E Spangenberg
author_sort Ladislav Palinkaš
collection DOAJ
description <p>The Ljubija ore deposits are the loci typici of siderite-barite-polysulphide deposits withinthe Inner Dinarides, Gemerides and Eastern Alps. Numerous sites of ore outcrops, smalleror larger ore bodies of mineralization, consisting of Fe carbonates, sulphides, barite andfluorite are scattered over an area of 150 square km. The half billion tons of iron ore resourcesoccur as replacement in dolostones and limestones, and as open-space fillings(veins, veinlets) in phyllites and sandstones. The genesis of the Ljubija ore deposits hasbeen explained as (i) syngenetic sedimentary-exhalative, (ii) hydrothermal-metasomatic inMiddle Triassic time or (iii) hydrothermal replacement of sedimentary carbonates in Permiantime. Basically two alternatives Variscan or Alpine metallogeny, frame the time of genesisfrom the Middle Carboniferous to the Middle Triassic. Genetic interpretation of theLjubija ore deposits required convincing arguments based on recent achievements of platetectonics. This contribution presents a set of new data on ore petrology, geochemistry, geologyand time of formation. The Ljubija ore field could justifiably be termed the &bdquo;Ljubijageothermal field&ldquo;, due to its areal extent and the thermal characteristics of numerous oredeposits and occurrences within the Sana-Una Palaeozoic terrain. The Ljubija geothermalfield marks the first signs of thermal instability of Pangea, revealing its breakdown along thedeep fractures and heralding incipient intracontinental rifting, the first phase of the newAlpine Wilson cycle. The research reveals novel data on the P-T-X characteristics of oreforming fluids (microthermometry, ion chromatography, Raman spectrometry), sulphur isotopes,maturity of organic matter by vitrinite reflection, and age determination by 40Ar/39Arand K-Ar methods. It adopts argumentatively all the estimated research parameters thatconstrain a justified genetic model.</p>
first_indexed 2024-12-21T18:59:37Z
format Article
id doaj.art-a5bd845bf2984a50bb8ac24cff813ac6
institution Directory Open Access Journal
issn 1330-030X
1333-4875
language English
last_indexed 2024-12-21T18:59:37Z
publishDate 2016-02-01
publisher Croatian Geological Survey
record_format Article
series Geologia Croatica
spelling doaj.art-a5bd845bf2984a50bb8ac24cff813ac62022-12-21T18:53:31ZengCroatian Geological SurveyGeologia Croatica1330-030X1333-48752016-02-0169133010.4154/GC.2016.02516The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)Ladislav PalinkašSibila Borojević ŠoštarićSabina Strmić PalinkašWalter ProchaskaZoltan PécskayFranz NeubauerJorge E Spangenberg<p>The Ljubija ore deposits are the loci typici of siderite-barite-polysulphide deposits withinthe Inner Dinarides, Gemerides and Eastern Alps. Numerous sites of ore outcrops, smalleror larger ore bodies of mineralization, consisting of Fe carbonates, sulphides, barite andfluorite are scattered over an area of 150 square km. The half billion tons of iron ore resourcesoccur as replacement in dolostones and limestones, and as open-space fillings(veins, veinlets) in phyllites and sandstones. The genesis of the Ljubija ore deposits hasbeen explained as (i) syngenetic sedimentary-exhalative, (ii) hydrothermal-metasomatic inMiddle Triassic time or (iii) hydrothermal replacement of sedimentary carbonates in Permiantime. Basically two alternatives Variscan or Alpine metallogeny, frame the time of genesisfrom the Middle Carboniferous to the Middle Triassic. Genetic interpretation of theLjubija ore deposits required convincing arguments based on recent achievements of platetectonics. This contribution presents a set of new data on ore petrology, geochemistry, geologyand time of formation. The Ljubija ore field could justifiably be termed the &bdquo;Ljubijageothermal field&ldquo;, due to its areal extent and the thermal characteristics of numerous oredeposits and occurrences within the Sana-Una Palaeozoic terrain. The Ljubija geothermalfield marks the first signs of thermal instability of Pangea, revealing its breakdown along thedeep fractures and heralding incipient intracontinental rifting, the first phase of the newAlpine Wilson cycle. The research reveals novel data on the P-T-X characteristics of oreforming fluids (microthermometry, ion chromatography, Raman spectrometry), sulphur isotopes,maturity of organic matter by vitrinite reflection, and age determination by 40Ar/39Arand K-Ar methods. It adopts argumentatively all the estimated research parameters thatconstrain a justified genetic model.</p>http://www.geologia-croatica.hr/ojs/index.php/GC/article/view/732Hydrothermal, metasomatic, geothermal, siderite, Permian
spellingShingle Ladislav Palinkaš
Sibila Borojević Šoštarić
Sabina Strmić Palinkaš
Walter Prochaska
Zoltan Pécskay
Franz Neubauer
Jorge E Spangenberg
The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
Geologia Croatica
Hydrothermal, metasomatic, geothermal, siderite, Permian
title The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
title_full The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
title_fullStr The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
title_full_unstemmed The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
title_short The Ljubija geothermal field: A herald of the Pangea break-up (NW Bosnia and Herzegovina)
title_sort ljubija geothermal field a herald of the pangea break up nw bosnia and herzegovina
topic Hydrothermal, metasomatic, geothermal, siderite, Permian
url http://www.geologia-croatica.hr/ojs/index.php/GC/article/view/732
work_keys_str_mv AT ladislavpalinkas theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT sibilaborojevicsostaric theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT sabinastrmicpalinkas theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT walterprochaska theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT zoltanpecskay theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT franzneubauer theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT jorgeespangenberg theljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT ladislavpalinkas ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT sibilaborojevicsostaric ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT sabinastrmicpalinkas ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT walterprochaska ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT zoltanpecskay ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT franzneubauer ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina
AT jorgeespangenberg ljubijageothermalfieldaheraldofthepangeabreakupnwbosniaandherzegovina