Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics

Palygorskite (Pal) is a kind of magnesium aluminum silicate clay mineral with a one-dimensional rod and layer chain structure. Herein, Pal hybrid iron oxide red pigment (Pal/ α -Fe _2 O _3 ) was prepared by the grinding method. Pal acted as a matrix to fix α -Fe _2 O _3 particles and influenced the...

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Main Authors: Yisen Han, Miao Shan, Yunfei Lu, Songqin Liu
Format: Article
Language:English
Published: IOP Publishing 2022-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ac7384
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author Yisen Han
Miao Shan
Yunfei Lu
Songqin Liu
author_facet Yisen Han
Miao Shan
Yunfei Lu
Songqin Liu
author_sort Yisen Han
collection DOAJ
description Palygorskite (Pal) is a kind of magnesium aluminum silicate clay mineral with a one-dimensional rod and layer chain structure. Herein, Pal hybrid iron oxide red pigment (Pal/ α -Fe _2 O _3 ) was prepared by the grinding method. Pal acted as a matrix to fix α -Fe _2 O _3 particles and influenced the performances of composite pigments by changing the particle size and distribution of α -Fe _2 O _3 . The color difference analysis showed that the color performances of composite pigments were closely related to the ratio of Pal to α -Fe _2 O _3 . Compared with the original red iron oxide pigment, the tinting strength of the composite pigment was increased by about 15%. When Pal/ α -Fe _2 O _3 was used as the red pigment for coating, it had good storage stability for waterborne coating and improved its adhesion and corrosion resistance. Pal/ α -Fe _2 O _3 composite pigments had excellent high-temperature resistance, which could increase the calcination temperature of ceramic pigments and would be beneficial for the ceramic industry. The synthetic method of Pal/ α -Fe _2 O _3 composite pigment was simple, low-cost, and environmentally friendly, and could be applied to large-scale industrial production.
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spelling doaj.art-a60300ce5558418e8c57deb9cf14a2cc2023-08-09T16:12:16ZengIOP PublishingMaterials Research Express2053-15912022-01-019606520210.1088/2053-1591/ac7384Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramicsYisen Han0Miao Shan1Yunfei Lu2Songqin Liu3https://orcid.org/0000-0002-4686-5291Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Device, Key Laboratory of Environmental Medicine Engineering, Ministry of Education, State Key Laboratory of Bioelectronics, School of Chemistry and Chemical Engineering, Southeast University , Nanjing 211189, People’s Republic of ChinaJiangsu Yuxing Industry and Trade Co., Ltd, Yixing, People’s Republic of ChinaJiangsu Yuxing Industry and Trade Co., Ltd, Yixing, People’s Republic of ChinaJiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Device, Key Laboratory of Environmental Medicine Engineering, Ministry of Education, State Key Laboratory of Bioelectronics, School of Chemistry and Chemical Engineering, Southeast University , Nanjing 211189, People’s Republic of ChinaPalygorskite (Pal) is a kind of magnesium aluminum silicate clay mineral with a one-dimensional rod and layer chain structure. Herein, Pal hybrid iron oxide red pigment (Pal/ α -Fe _2 O _3 ) was prepared by the grinding method. Pal acted as a matrix to fix α -Fe _2 O _3 particles and influenced the performances of composite pigments by changing the particle size and distribution of α -Fe _2 O _3 . The color difference analysis showed that the color performances of composite pigments were closely related to the ratio of Pal to α -Fe _2 O _3 . Compared with the original red iron oxide pigment, the tinting strength of the composite pigment was increased by about 15%. When Pal/ α -Fe _2 O _3 was used as the red pigment for coating, it had good storage stability for waterborne coating and improved its adhesion and corrosion resistance. Pal/ α -Fe _2 O _3 composite pigments had excellent high-temperature resistance, which could increase the calcination temperature of ceramic pigments and would be beneficial for the ceramic industry. The synthetic method of Pal/ α -Fe _2 O _3 composite pigment was simple, low-cost, and environmentally friendly, and could be applied to large-scale industrial production.https://doi.org/10.1088/2053-1591/ac7384iron oxide red pigmentPalygorskitePalygorskite hybrid iron oxide red pigmentcolor difference analysispaintceramic
spellingShingle Yisen Han
Miao Shan
Yunfei Lu
Songqin Liu
Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
Materials Research Express
iron oxide red pigment
Palygorskite
Palygorskite hybrid iron oxide red pigment
color difference analysis
paint
ceramic
title Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
title_full Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
title_fullStr Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
title_full_unstemmed Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
title_short Preparation of Palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
title_sort preparation of palygorskite hybrid iron oxide red pigment and its application in waterborne polyurethane composite coatings and ceramics
topic iron oxide red pigment
Palygorskite
Palygorskite hybrid iron oxide red pigment
color difference analysis
paint
ceramic
url https://doi.org/10.1088/2053-1591/ac7384
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AT yunfeilu preparationofpalygorskitehybridironoxideredpigmentanditsapplicationinwaterbornepolyurethanecompositecoatingsandceramics
AT songqinliu preparationofpalygorskitehybridironoxideredpigmentanditsapplicationinwaterbornepolyurethanecompositecoatingsandceramics