Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid
We report the synthesis, structure, and magnetic properties of a new dinuclear dysprosium(III) complex based on a 3-methoxycinnamate ligand. The centrosymmetric complex exhibits a field-induced SMM behavior. In contrast to the previously reported lanthanide-based systems with cinnamate derivatives t...
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-03-01
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| Series: | Inorganics |
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| Online Access: | http://www.mdpi.com/2304-6740/6/1/35 |
| _version_ | 1818216766223941632 |
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| author | Ouafa Khalfaoui Adel Beghidja Jérôme Long Chahrazed Beghidja Yannick Guari Joulia Larionova |
| author_facet | Ouafa Khalfaoui Adel Beghidja Jérôme Long Chahrazed Beghidja Yannick Guari Joulia Larionova |
| author_sort | Ouafa Khalfaoui |
| collection | DOAJ |
| description | We report the synthesis, structure, and magnetic properties of a new dinuclear dysprosium(III) complex based on a 3-methoxycinnamate ligand. The centrosymmetric complex exhibits a field-induced SMM behavior. In contrast to the previously reported lanthanide-based systems with cinnamate derivatives that relax through a combination of Raman and direct processes, an Orbach process is also involved in highlighting the role of the structural organization over the spin-lattice relaxations. |
| first_indexed | 2024-12-12T06:57:11Z |
| format | Article |
| id | doaj.art-a6197c179e8148d5b1fd2eec132111ae |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-12-12T06:57:11Z |
| publishDate | 2018-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-a6197c179e8148d5b1fd2eec132111ae2022-12-22T00:33:55ZengMDPI AGInorganics2304-67402018-03-01613510.3390/inorganics6010035inorganics6010035Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic AcidOuafa Khalfaoui0Adel Beghidja1Jérôme Long2Chahrazed Beghidja3Yannick Guari4Joulia Larionova5Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine, Route Aïn elbey, Constantine 25000, AlgeriaUnité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine, Route Aïn elbey, Constantine 25000, AlgeriaInstitut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objects, Université de Montpellier, ENSCM, CNRS, Place E. Bataillon, 34095 Montpellier, FranceUnité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine, Route Aïn elbey, Constantine 25000, AlgeriaInstitut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objects, Université de Montpellier, ENSCM, CNRS, Place E. Bataillon, 34095 Montpellier, FranceInstitut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objects, Université de Montpellier, ENSCM, CNRS, Place E. Bataillon, 34095 Montpellier, FranceWe report the synthesis, structure, and magnetic properties of a new dinuclear dysprosium(III) complex based on a 3-methoxycinnamate ligand. The centrosymmetric complex exhibits a field-induced SMM behavior. In contrast to the previously reported lanthanide-based systems with cinnamate derivatives that relax through a combination of Raman and direct processes, an Orbach process is also involved in highlighting the role of the structural organization over the spin-lattice relaxations.http://www.mdpi.com/2304-6740/6/1/35lanthanide ionssingle-molecule magnetmagnetic relaxationsingle-crystal structure |
| spellingShingle | Ouafa Khalfaoui Adel Beghidja Jérôme Long Chahrazed Beghidja Yannick Guari Joulia Larionova Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid Inorganics lanthanide ions single-molecule magnet magnetic relaxation single-crystal structure |
| title | Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid |
| title_full | Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid |
| title_fullStr | Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid |
| title_full_unstemmed | Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid |
| title_short | Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid |
| title_sort | field induced slow relaxation in a dinuclear dysprosium iii complex based on 3 methoxycinnamic acid |
| topic | lanthanide ions single-molecule magnet magnetic relaxation single-crystal structure |
| url | http://www.mdpi.com/2304-6740/6/1/35 |
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