Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data

Paper materials and works of art on paper such as drawings, watercolors, prints, books, and manuscripts represent a large portion of museum, archive, and library collections. However, paper materials are infrequently the subject of technical studies due to inherent limitations in their analysis such...

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Main Authors: Julie H. Wertz, Arthur A. McClelland, Debora D. Mayer, Penley Knipe
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Heritage
Subjects:
Online Access:https://www.mdpi.com/2571-9408/5/3/102
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author Julie H. Wertz
Arthur A. McClelland
Debora D. Mayer
Penley Knipe
author_facet Julie H. Wertz
Arthur A. McClelland
Debora D. Mayer
Penley Knipe
author_sort Julie H. Wertz
collection DOAJ
description Paper materials and works of art on paper such as drawings, watercolors, prints, books, and manuscripts represent a large portion of museum, archive, and library collections. However, paper materials are infrequently the subject of technical studies due to inherent limitations in their analysis such as the fragility of the paper substrate, a lack of suitable sampling opportunities, and the presence of mixed, but chemically similar cellulosic materials. The application of principal component analysis (PCA) modeling to specular reflection FTIR data has the potential to provide a non-invasive means of analysis for major and minor components in paper materials. Using known study collection objects, PCA models distinguishing paper sizing materials and fiber types based on specular reflection FTIR data were successfully demonstrated thus providing a plausible alternative method for the identification of paper materials in collection objects without the need for destructive testing or sampling of the object.
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spelling doaj.art-a619ec8e37db4cf09c5c7aa7244e97eb2023-11-23T16:32:20ZengMDPI AGHeritage2571-94082022-08-01531960197310.3390/heritage5030102Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR DataJulie H. Wertz0Arthur A. McClelland1Debora D. Mayer2Penley Knipe3Straus Center for Conservation and Technical Studies, Harvard Art Museums, Cambridge, MA 02138, USACenter for Nanoscale Systems, Harvard University, Cambridge, MA 02138, USAWeissman Preservation Center, Harvard University, Cambridge, MA 02138, USAStraus Center for Conservation and Technical Studies, Harvard Art Museums, Cambridge, MA 02138, USAPaper materials and works of art on paper such as drawings, watercolors, prints, books, and manuscripts represent a large portion of museum, archive, and library collections. However, paper materials are infrequently the subject of technical studies due to inherent limitations in their analysis such as the fragility of the paper substrate, a lack of suitable sampling opportunities, and the presence of mixed, but chemically similar cellulosic materials. The application of principal component analysis (PCA) modeling to specular reflection FTIR data has the potential to provide a non-invasive means of analysis for major and minor components in paper materials. Using known study collection objects, PCA models distinguishing paper sizing materials and fiber types based on specular reflection FTIR data were successfully demonstrated thus providing a plausible alternative method for the identification of paper materials in collection objects without the need for destructive testing or sampling of the object.https://www.mdpi.com/2571-9408/5/3/102specular reflection FTIRprincipal component analysis PCApaper fiber identificationpaper sizing identification
spellingShingle Julie H. Wertz
Arthur A. McClelland
Debora D. Mayer
Penley Knipe
Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
Heritage
specular reflection FTIR
principal component analysis PCA
paper fiber identification
paper sizing identification
title Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
title_full Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
title_fullStr Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
title_full_unstemmed Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
title_short Modeling Chemical Tests and Fiber Identification of Paper Materials Using Principal Component Analysis and Specular Reflection FTIR Data
title_sort modeling chemical tests and fiber identification of paper materials using principal component analysis and specular reflection ftir data
topic specular reflection FTIR
principal component analysis PCA
paper fiber identification
paper sizing identification
url https://www.mdpi.com/2571-9408/5/3/102
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