Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea

This paper presents the results of geochemical and acoustic investigations of sediments in the Polish sector of the southern Baltic Sea. Its objective was toindicate areas of gas bubble formation and the occurrence of methane. Over 3000 nautical miles of transects were recorded using a variety of hy...

Full description

Bibliographic Details
Main Authors: Aleksandra Brodecka, Piotr Majewski, Jerzy Bolałek, Zygmunt Klusek
Format: Article
Language:English
Published: Elsevier 2013-11-01
Series:Oceanologia
Subjects:
Online Access:http://www.iopan.gda.pl/oceanologia/55_4.html#A10
_version_ 1818154728552398848
author Aleksandra Brodecka
Piotr Majewski
Jerzy Bolałek
Zygmunt Klusek
author_facet Aleksandra Brodecka
Piotr Majewski
Jerzy Bolałek
Zygmunt Klusek
author_sort Aleksandra Brodecka
collection DOAJ
description This paper presents the results of geochemical and acoustic investigations of sediments in the Polish sector of the southern Baltic Sea. Its objective was toindicate areas of gas bubble formation and the occurrence of methane. Over 3000 nautical miles of transects were recorded using a variety of hydroacousticinstruments, and five coring points were selected for further analyses of pore waters(CH<sub style="font-size:0.6em">4</sub>, SO<sub style="font-size:0.6em">4</sub><sup style="font-size:0.6em">-2</sup>, H<sub style="font-size:0.6em">2</sub>S, NH<sub style="font-size:0.6em">4</sub><sup style="font-size:0.6em">+</sup>, total alkalinity) and sediments (grain size distribution,C<sub style="font-size:0.6em">org</sub>, N<sub style="font-size:0.6em">tot</sub>, LOI and WC). Gas turned out to be present at shallow depths in different forms such as recent and buried pockmarks, and gas-saturated sediments (including gas pockets and seepages). It was found that methane was widespread in the sediments of the study area, both in the surface sediments, e.g. in the vicinity of the Hel Peninsula or in the central Gulf of Gdańsk, and in deeper sediment layers, e.g. in the Gdańsk Deep and the Słupsk Furrow. Chemical analysis showed that as a result of the rapid decomposition of organic matter, sulphates were depleted in the top 20 cm layer of sediments and that methane was produced at relatively shallow depths (in some areas even at depths of 20-30 cm bsf) compared to other regions of the Baltic, reaching concentrations of &gt;6 mmol l<sup style="font-size:0.6em">-1</sup> in the 30-40 cm layer below the sediment surface. The sulphate-methane transition zone (SMTZ) was 4-37 cm thick and was situated in the uppermost 50 cm of the sediments.
first_indexed 2024-12-11T14:31:07Z
format Article
id doaj.art-a64bc559ca3846a9993f15bf583506be
institution Directory Open Access Journal
issn 0078-3234
language English
last_indexed 2024-12-11T14:31:07Z
publishDate 2013-11-01
publisher Elsevier
record_format Article
series Oceanologia
spelling doaj.art-a64bc559ca3846a9993f15bf583506be2022-12-22T01:02:24ZengElsevierOceanologia0078-32342013-11-01554951978http://dx.doi.org/10.5697/oc.55-4.951Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic SeaAleksandra BrodeckaPiotr MajewskiJerzy BolałekZygmunt KlusekThis paper presents the results of geochemical and acoustic investigations of sediments in the Polish sector of the southern Baltic Sea. Its objective was toindicate areas of gas bubble formation and the occurrence of methane. Over 3000 nautical miles of transects were recorded using a variety of hydroacousticinstruments, and five coring points were selected for further analyses of pore waters(CH<sub style="font-size:0.6em">4</sub>, SO<sub style="font-size:0.6em">4</sub><sup style="font-size:0.6em">-2</sup>, H<sub style="font-size:0.6em">2</sub>S, NH<sub style="font-size:0.6em">4</sub><sup style="font-size:0.6em">+</sup>, total alkalinity) and sediments (grain size distribution,C<sub style="font-size:0.6em">org</sub>, N<sub style="font-size:0.6em">tot</sub>, LOI and WC). Gas turned out to be present at shallow depths in different forms such as recent and buried pockmarks, and gas-saturated sediments (including gas pockets and seepages). It was found that methane was widespread in the sediments of the study area, both in the surface sediments, e.g. in the vicinity of the Hel Peninsula or in the central Gulf of Gdańsk, and in deeper sediment layers, e.g. in the Gdańsk Deep and the Słupsk Furrow. Chemical analysis showed that as a result of the rapid decomposition of organic matter, sulphates were depleted in the top 20 cm layer of sediments and that methane was produced at relatively shallow depths (in some areas even at depths of 20-30 cm bsf) compared to other regions of the Baltic, reaching concentrations of &gt;6 mmol l<sup style="font-size:0.6em">-1</sup> in the 30-40 cm layer below the sediment surface. The sulphate-methane transition zone (SMTZ) was 4-37 cm thick and was situated in the uppermost 50 cm of the sediments.http://www.iopan.gda.pl/oceanologia/55_4.html#A10MethaneSedimentsSouthern BalticGas bubblesSMTZ
spellingShingle Aleksandra Brodecka
Piotr Majewski
Jerzy Bolałek
Zygmunt Klusek
Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
Oceanologia
Methane
Sediments
Southern Baltic
Gas bubbles
SMTZ
title Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
title_full Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
title_fullStr Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
title_full_unstemmed Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
title_short Geochemical and acoustic evidence for the occurrence of methane in sediments of the Polish sector of the southern Baltic Sea
title_sort geochemical and acoustic evidence for the occurrence of methane in sediments of the polish sector of the southern baltic sea
topic Methane
Sediments
Southern Baltic
Gas bubbles
SMTZ
url http://www.iopan.gda.pl/oceanologia/55_4.html#A10
work_keys_str_mv AT aleksandrabrodecka geochemicalandacousticevidencefortheoccurrenceofmethaneinsedimentsofthepolishsectorofthesouthernbalticsea
AT piotrmajewski geochemicalandacousticevidencefortheoccurrenceofmethaneinsedimentsofthepolishsectorofthesouthernbalticsea
AT jerzybolałek geochemicalandacousticevidencefortheoccurrenceofmethaneinsedimentsofthepolishsectorofthesouthernbalticsea
AT zygmuntklusek geochemicalandacousticevidencefortheoccurrenceofmethaneinsedimentsofthepolishsectorofthesouthernbalticsea