Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand

Volatile organic compounds (VOCs) play an important role in atmospheric chemistry due to their high reactivity—reacting photochemically with oxides of nitrogen (NOx) in the presence of solar radiation forming tropospheric ozone (O3). Each VOC species have different effects on ozone formation accord...

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Main Authors: Narita Fakkaew, Surat Bualert, Thunyapat Thongyen, Thitima Rungratanaubon
Format: Article
Language:English
Published: Environmental Research Institute, Chulalongkorn University 2021-09-01
Series:Applied Environmental Research
Subjects:
Online Access:https://ph01-ohno.tci-thaijo.org/index.php/aer/article/view/245462
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author Narita Fakkaew
Surat Bualert
Thunyapat Thongyen
Thitima Rungratanaubon
author_facet Narita Fakkaew
Surat Bualert
Thunyapat Thongyen
Thitima Rungratanaubon
author_sort Narita Fakkaew
collection DOAJ
description Volatile organic compounds (VOCs) play an important role in atmospheric chemistry due to their high reactivity—reacting photochemically with oxides of nitrogen (NOx) in the presence of solar radiation forming tropospheric ozone (O3). Each VOC species have different effects on ozone formation according to the rates and pathways of their reactions. The objective of this study aims to examine ozone formation from the estimation of ozone formation potential (OFP). The observation of 29 VOCs species was carried out in the urban area near the roads of Bangkok, Thailand. Measurements were carried out during the dry season, from 16th February to 15th March, 2018. The air samples were analyzed using gas chromatography flame ionization detector (GC-FID). The results showed that toluene had the highest VOCs concentration followed by propane, and carbon tetrachloride (CCl4). The average ratio of benzene to toluene (B/T) and toluene to benzene (T/B) indicate that both toluene and benzene emitted from industrial area and vehicular emission. Ratio of m/p-xylene to benzene (m/p-X/B) indicate that BTEX emitted far from the source. The ozone formation potential indicated that toluene was the main VOC contributing to the total ozone formation. High VOCs concentration in monitoring site was influenced by vehicular sources and the sea breeze brought the pollutants back to the land.
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spelling doaj.art-a668ddd2e267449f8713265de16a5c712022-12-22T01:37:40ZengEnvironmental Research Institute, Chulalongkorn UniversityApplied Environmental Research2287-07412287-075X2021-09-01434Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, ThailandNarita Fakkaew0Surat Bualert1Thunyapat Thongyen2Thitima Rungratanaubon3Faculty of Environment, Kasetsart University, Bangkok, ThailandFaculty of Environment, Kasetsart University, Bangkok, ThailandFaculty of Environment, Kasetsart University, Bangkok, ThailandFaculty of Environment, Kasetsart University, Bangkok, Thailand Volatile organic compounds (VOCs) play an important role in atmospheric chemistry due to their high reactivity—reacting photochemically with oxides of nitrogen (NOx) in the presence of solar radiation forming tropospheric ozone (O3). Each VOC species have different effects on ozone formation according to the rates and pathways of their reactions. The objective of this study aims to examine ozone formation from the estimation of ozone formation potential (OFP). The observation of 29 VOCs species was carried out in the urban area near the roads of Bangkok, Thailand. Measurements were carried out during the dry season, from 16th February to 15th March, 2018. The air samples were analyzed using gas chromatography flame ionization detector (GC-FID). The results showed that toluene had the highest VOCs concentration followed by propane, and carbon tetrachloride (CCl4). The average ratio of benzene to toluene (B/T) and toluene to benzene (T/B) indicate that both toluene and benzene emitted from industrial area and vehicular emission. Ratio of m/p-xylene to benzene (m/p-X/B) indicate that BTEX emitted far from the source. The ozone formation potential indicated that toluene was the main VOC contributing to the total ozone formation. High VOCs concentration in monitoring site was influenced by vehicular sources and the sea breeze brought the pollutants back to the land. https://ph01-ohno.tci-thaijo.org/index.php/aer/article/view/245462Ozone formation potentialUrban areaBangkokVolatile organic compoundsVehicle exhausts
spellingShingle Narita Fakkaew
Surat Bualert
Thunyapat Thongyen
Thitima Rungratanaubon
Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
Applied Environmental Research
Ozone formation potential
Urban area
Bangkok
Volatile organic compounds
Vehicle exhausts
title Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
title_full Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
title_fullStr Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
title_full_unstemmed Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
title_short Ozone Formation Potential of Ambient Volatile Organic Compounds at Roadside in Bangkok, Thailand
title_sort ozone formation potential of ambient volatile organic compounds at roadside in bangkok thailand
topic Ozone formation potential
Urban area
Bangkok
Volatile organic compounds
Vehicle exhausts
url https://ph01-ohno.tci-thaijo.org/index.php/aer/article/view/245462
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AT suratbualert ozoneformationpotentialofambientvolatileorganiccompoundsatroadsideinbangkokthailand
AT thunyapatthongyen ozoneformationpotentialofambientvolatileorganiccompoundsatroadsideinbangkokthailand
AT thitimarungratanaubon ozoneformationpotentialofambientvolatileorganiccompoundsatroadsideinbangkokthailand