Corrosivity of Different Natural Groundwaters from Repository Sites

In Finland, the repositories for low- and intermediate-level waste (LLW and ILW) are situated in three different geographical locations in deep granite bedrock, where waste containers can be subjected to anoxic groundwater containing microbes. The composition of groundwater varies in terms of chemis...

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Main Authors: Mervi Somervuori, Elisa Isotahdon, Maija Nuppunen-Puputti, Malin Bomberg, Leena Carpén, Pauliina Rajala
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Materials Proceedings
Subjects:
Online Access:https://www.mdpi.com/2673-4605/6/1/33
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author Mervi Somervuori
Elisa Isotahdon
Maija Nuppunen-Puputti
Malin Bomberg
Leena Carpén
Pauliina Rajala
author_facet Mervi Somervuori
Elisa Isotahdon
Maija Nuppunen-Puputti
Malin Bomberg
Leena Carpén
Pauliina Rajala
author_sort Mervi Somervuori
collection DOAJ
description In Finland, the repositories for low- and intermediate-level waste (LLW and ILW) are situated in three different geographical locations in deep granite bedrock, where waste containers can be subjected to anoxic groundwater containing microbes. The composition of groundwater varies in terms of chemistry and microbial activity in different locations. In this study, groundwater from three repository areas was analyzed with regard to chemistry and microbial community. The corrosion tendency of three steel grades, carbon steel AISI/SAE 1005 and stainless steels AISI 304 and 316L, was studied in these groundwater environments using electrochemical methods. As a reference, measurements were also performed in simulated groundwater that did not contain microbes. The measurements show that the corrosivity of the water, and thus, the steels’ performance, differed depending on its location of origin. Additionally, the groundwater differed remarkably in their chemical composition as well as the abundance and diversity of the microbial community within them. Consequently, the local environment has to be considered when evaluating the long-term safety of the disposal of nuclear waste.
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spelling doaj.art-a673d9a7e2164fbbb22a965d294e6e982023-11-19T11:47:46ZengMDPI AGMaterials Proceedings2673-46052021-05-01613310.3390/CMDWC2021-10064Corrosivity of Different Natural Groundwaters from Repository SitesMervi Somervuori0Elisa Isotahdon1Maija Nuppunen-Puputti2Malin Bomberg3Leena Carpén4Pauliina Rajala5VTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandVTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandVTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandVTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandVTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandVTT Technical Research Centre of Finland Ltd., 02150 Espoo, FinlandIn Finland, the repositories for low- and intermediate-level waste (LLW and ILW) are situated in three different geographical locations in deep granite bedrock, where waste containers can be subjected to anoxic groundwater containing microbes. The composition of groundwater varies in terms of chemistry and microbial activity in different locations. In this study, groundwater from three repository areas was analyzed with regard to chemistry and microbial community. The corrosion tendency of three steel grades, carbon steel AISI/SAE 1005 and stainless steels AISI 304 and 316L, was studied in these groundwater environments using electrochemical methods. As a reference, measurements were also performed in simulated groundwater that did not contain microbes. The measurements show that the corrosivity of the water, and thus, the steels’ performance, differed depending on its location of origin. Additionally, the groundwater differed remarkably in their chemical composition as well as the abundance and diversity of the microbial community within them. Consequently, the local environment has to be considered when evaluating the long-term safety of the disposal of nuclear waste.https://www.mdpi.com/2673-4605/6/1/33corrosiongroundwatersteelLLWILW
spellingShingle Mervi Somervuori
Elisa Isotahdon
Maija Nuppunen-Puputti
Malin Bomberg
Leena Carpén
Pauliina Rajala
Corrosivity of Different Natural Groundwaters from Repository Sites
Materials Proceedings
corrosion
groundwater
steel
LLW
ILW
title Corrosivity of Different Natural Groundwaters from Repository Sites
title_full Corrosivity of Different Natural Groundwaters from Repository Sites
title_fullStr Corrosivity of Different Natural Groundwaters from Repository Sites
title_full_unstemmed Corrosivity of Different Natural Groundwaters from Repository Sites
title_short Corrosivity of Different Natural Groundwaters from Repository Sites
title_sort corrosivity of different natural groundwaters from repository sites
topic corrosion
groundwater
steel
LLW
ILW
url https://www.mdpi.com/2673-4605/6/1/33
work_keys_str_mv AT mervisomervuori corrosivityofdifferentnaturalgroundwatersfromrepositorysites
AT elisaisotahdon corrosivityofdifferentnaturalgroundwatersfromrepositorysites
AT maijanuppunenpuputti corrosivityofdifferentnaturalgroundwatersfromrepositorysites
AT malinbomberg corrosivityofdifferentnaturalgroundwatersfromrepositorysites
AT leenacarpen corrosivityofdifferentnaturalgroundwatersfromrepositorysites
AT pauliinarajala corrosivityofdifferentnaturalgroundwatersfromrepositorysites