Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate
The title compound, [Zn(SO4)(C10H8N2)2]·C2H6O2, is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The ZnII atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine li...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809055433 |
| _version_ | 1819105179263303680 |
|---|---|
| author | Kai-Long Zhong |
| author_facet | Kai-Long Zhong |
| author_sort | Kai-Long Zhong |
| collection | DOAJ |
| description | The title compound, [Zn(SO4)(C10H8N2)2]·C2H6O2, is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The ZnII atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO4(C10H8N2)2] and C2H6O2 units are connected by intermolecular O—H...O hydrogen bonding, which leads to additional stabilization of the structure. |
| first_indexed | 2024-12-22T02:18:08Z |
| format | Article |
| id | doaj.art-a68b659248a545bd8a77f8cf294b5762 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:18:08Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a68b659248a545bd8a77f8cf294b57622022-12-21T18:42:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m131m13110.1107/S1600536809055433Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvateKai-Long ZhongThe title compound, [Zn(SO4)(C10H8N2)2]·C2H6O2, is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The ZnII atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO4(C10H8N2)2] and C2H6O2 units are connected by intermolecular O—H...O hydrogen bonding, which leads to additional stabilization of the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809055433 |
| spellingShingle | Kai-Long Zhong Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate Acta Crystallographica Section E |
| title | Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate |
| title_full | Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate |
| title_fullStr | Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate |
| title_full_unstemmed | Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate |
| title_short | Bis(2,2′-bipyridyl-κ2N,N′)(sulfato-κ2O,O′)zinc(II) ethane-1,2-diol solvate |
| title_sort | bis 2 2 amp 8242 bipyridyl amp 954 2n n amp 8242 sulfato amp 954 2o o amp 8242 zinc ii ethane 1 2 diol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809055433 |
| work_keys_str_mv | AT kailongzhong bis22amp8242bipyridylamp9542nnamp8242sulfatoamp9542ooamp8242zinciiethane12diolsolvate |