Isoconversional kinetic analysis of the alkyd/melamine resins curing
The curing reaction for the mixtures of alkyd resins based on ricinoleic acid, phthalic anhydride and three polyols (glycerin, trimethylolpropane or ethoxylated pentaerythritol) with two different commercial melamine resins was investigated by differential scanning calorimetry (DSC). The curing...
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| Format: | Article |
| Language: | English |
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Association of the Chemical Engineers of Serbia
2013-01-01
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| Series: | Chemical Industry and Chemical Engineering Quarterly |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1451-9372/2013/1451-93721200059J.pdf |
| _version_ | 1818305487118008320 |
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| author | Jovičić Mirjana Radičević Radmila Pavličević Jelena Bera Oskar |
| author_facet | Jovičić Mirjana Radičević Radmila Pavličević Jelena Bera Oskar |
| author_sort | Jovičić Mirjana |
| collection | DOAJ |
| description | The curing reaction for the mixtures of alkyd resins based on ricinoleic acid, phthalic anhydride and three polyols (glycerin, trimethylolpropane or ethoxylated pentaerythritol) with two different commercial melamine resins was investigated by differential scanning calorimetry (DSC). The curing kinetics analysis was performed using the isoconversional methods (Ozawa-Flynn-Wall, Kissinger-Akahira-Sunose and Friedman). Isoconversional methods were carried out with three heating rates (5, 10 and 20°C/min) in a scanning temperature range from 40 to 250°C. It was found that the curing activation energy of resin mixtures is influenced by alkyd and melamine resin type due to the catalytic effect of hydroxyl group on the reactions. The dependence of apparent curing degree on time, which was obtained by mathematical transformations of dynamic DSC data using Ozawa-Flynn-Wall method, describes well the isothermal DSC experiments. |
| first_indexed | 2024-12-13T06:27:22Z |
| format | Article |
| id | doaj.art-a6a4fb58166f4fd4af4caa8c3ffd1edb |
| institution | Directory Open Access Journal |
| issn | 1451-9372 2217-7434 |
| language | English |
| last_indexed | 2024-12-13T06:27:22Z |
| publishDate | 2013-01-01 |
| publisher | Association of the Chemical Engineers of Serbia |
| record_format | Article |
| series | Chemical Industry and Chemical Engineering Quarterly |
| spelling | doaj.art-a6a4fb58166f4fd4af4caa8c3ffd1edb2022-12-21T23:56:42ZengAssociation of the Chemical Engineers of SerbiaChemical Industry and Chemical Engineering Quarterly1451-93722217-74342013-01-0119225326210.2298/CICEQ111110059JIsoconversional kinetic analysis of the alkyd/melamine resins curingJovičić MirjanaRadičević RadmilaPavličević JelenaBera OskarThe curing reaction for the mixtures of alkyd resins based on ricinoleic acid, phthalic anhydride and three polyols (glycerin, trimethylolpropane or ethoxylated pentaerythritol) with two different commercial melamine resins was investigated by differential scanning calorimetry (DSC). The curing kinetics analysis was performed using the isoconversional methods (Ozawa-Flynn-Wall, Kissinger-Akahira-Sunose and Friedman). Isoconversional methods were carried out with three heating rates (5, 10 and 20°C/min) in a scanning temperature range from 40 to 250°C. It was found that the curing activation energy of resin mixtures is influenced by alkyd and melamine resin type due to the catalytic effect of hydroxyl group on the reactions. The dependence of apparent curing degree on time, which was obtained by mathematical transformations of dynamic DSC data using Ozawa-Flynn-Wall method, describes well the isothermal DSC experiments.http://www.doiserbia.nb.rs/img/doi/1451-9372/2013/1451-93721200059J.pdfcoatingthermosetting resinscuringDSCisoconversional methods |
| spellingShingle | Jovičić Mirjana Radičević Radmila Pavličević Jelena Bera Oskar Isoconversional kinetic analysis of the alkyd/melamine resins curing Chemical Industry and Chemical Engineering Quarterly coating thermosetting resins curing DSC isoconversional methods |
| title | Isoconversional kinetic analysis of the alkyd/melamine resins curing |
| title_full | Isoconversional kinetic analysis of the alkyd/melamine resins curing |
| title_fullStr | Isoconversional kinetic analysis of the alkyd/melamine resins curing |
| title_full_unstemmed | Isoconversional kinetic analysis of the alkyd/melamine resins curing |
| title_short | Isoconversional kinetic analysis of the alkyd/melamine resins curing |
| title_sort | isoconversional kinetic analysis of the alkyd melamine resins curing |
| topic | coating thermosetting resins curing DSC isoconversional methods |
| url | http://www.doiserbia.nb.rs/img/doi/1451-9372/2013/1451-93721200059J.pdf |
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