(η5-Carboxycyclopentadienyl)(η7-cycloheptatrienyl)manganese(I) hexafluoridophosphate

(η5-Carboxycyclopentadienyl)(η7-cycloheptatrienyl)manganese(I) hexafluoridophosphate

The title compound, [Mn(C7H7)(C6H5O2)]PF6 or [(Cht)Mn(Cp'CO2H)]PF6, with Cht = cycloheptatrienyl and Cp' = C5H4, is an air-stable, purple, heteroleptic, cationic sandwich complex with manganese in oxidation state +I and π-coordinating cycloheptatrienyl and cyclopentadienyl ligands. The lat...

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Bibliographic Details
Main Authors:	Reinhard Thaler, Klaus Wurst, Benno Bildstein
Format:	Article
Language:	English
Published:	International Union of Crystallography 2023-02-01
Series:	IUCrData
Subjects:	tromancenium manganese cationic carboxylic acid heteroleptic sandwich complexes carboxylic acid sandwich complexes crystal structure
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2414314623001074

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