Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering

In this work, diamond-like carbon (DLC) films used as anti-reflective coatings for monocrystalline silicon were deposited by magnetron sputtering for potential application in solar cells. The microstructural and optical properties of the films were investigated as a function of substrate temperature...

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Main Authors: Xin Tan, Hang Zhai, Keke Meng, Zhongyi Zhang
Format: Article
Language:English
Published: IOP Publishing 2021-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ac2445
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author Xin Tan
Hang Zhai
Keke Meng
Zhongyi Zhang
author_facet Xin Tan
Hang Zhai
Keke Meng
Zhongyi Zhang
author_sort Xin Tan
collection DOAJ
description In this work, diamond-like carbon (DLC) films used as anti-reflective coatings for monocrystalline silicon were deposited by magnetron sputtering for potential application in solar cells. The microstructural and optical properties of the films were investigated as a function of substrate temperature over a wide range during deposition. It showed that, when the substrate temperature increased from RT to 800 °C, the hybridized structures of the DLC films accordingly changed associated with a significant variation of refractive index between2.22 and 1.64 at a wavelength of 550 nm. Three types of coating systems, namely single-, three- and five-layer films on monocrystalline silicon substrates, were designed based on the anti-reflection principle and fabricated in terms of the relationships of refractive index and deposition rate with substrate temperature. In particular, a well-designed three-layer film, of which the refractive index gradually changed along the thickness, that is 1.8, 1.9 and 2.0, respectively, was successfully deposited at one step on monocrystalline silicon substrates by adjusting substrate temperature and deposition time, and featured a broadband anti-reflective characteristic with low average reflectivity of 8.7% at a wide solar spectrum of 400–1100 nm. This work demonstrates that the DLC film has a promising application potential as broadband anti-reflective coatings in silicon-based solar cells.
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spelling doaj.art-a6bd82c11ee94298880a3e38c471318b2023-08-09T15:52:19ZengIOP PublishingMaterials Research Express2053-15912021-01-018909640210.1088/2053-1591/ac2445Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputteringXin Tan0https://orcid.org/0000-0001-8314-8032Hang Zhai1Keke Meng2Zhongyi Zhang3College of Mechanical Engineering, Inner Mongolia University of Science & Technology , Baotou 014010, People’s Republic of ChinaCollege of Mechanical Engineering, Inner Mongolia University of Science & Technology , Baotou 014010, People’s Republic of ChinaCollege of Mechanical Engineering, Inner Mongolia University of Science & Technology , Baotou 014010, People’s Republic of ChinaCollege of Mechanical Engineering, Inner Mongolia University of Science & Technology , Baotou 014010, People’s Republic of ChinaIn this work, diamond-like carbon (DLC) films used as anti-reflective coatings for monocrystalline silicon were deposited by magnetron sputtering for potential application in solar cells. The microstructural and optical properties of the films were investigated as a function of substrate temperature over a wide range during deposition. It showed that, when the substrate temperature increased from RT to 800 °C, the hybridized structures of the DLC films accordingly changed associated with a significant variation of refractive index between2.22 and 1.64 at a wavelength of 550 nm. Three types of coating systems, namely single-, three- and five-layer films on monocrystalline silicon substrates, were designed based on the anti-reflection principle and fabricated in terms of the relationships of refractive index and deposition rate with substrate temperature. In particular, a well-designed three-layer film, of which the refractive index gradually changed along the thickness, that is 1.8, 1.9 and 2.0, respectively, was successfully deposited at one step on monocrystalline silicon substrates by adjusting substrate temperature and deposition time, and featured a broadband anti-reflective characteristic with low average reflectivity of 8.7% at a wide solar spectrum of 400–1100 nm. This work demonstrates that the DLC film has a promising application potential as broadband anti-reflective coatings in silicon-based solar cells.https://doi.org/10.1088/2053-1591/ac2445diamond-like carbonmagnetron sputteringmicrostructural evolutionoptical propertiesanti-reflective coating
spellingShingle Xin Tan
Hang Zhai
Keke Meng
Zhongyi Zhang
Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
Materials Research Express
diamond-like carbon
magnetron sputtering
microstructural evolution
optical properties
anti-reflective coating
title Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
title_full Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
title_fullStr Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
title_full_unstemmed Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
title_short Anti-reflection for monocrystalline silicon from diamond-like carbon films deposited by magnetron sputtering
title_sort anti reflection for monocrystalline silicon from diamond like carbon films deposited by magnetron sputtering
topic diamond-like carbon
magnetron sputtering
microstructural evolution
optical properties
anti-reflective coating
url https://doi.org/10.1088/2053-1591/ac2445
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AT hangzhai antireflectionformonocrystallinesiliconfromdiamondlikecarbonfilmsdepositedbymagnetronsputtering
AT kekemeng antireflectionformonocrystallinesiliconfromdiamondlikecarbonfilmsdepositedbymagnetronsputtering
AT zhongyizhang antireflectionformonocrystallinesiliconfromdiamondlikecarbonfilmsdepositedbymagnetronsputtering