Crystal structure of [tBuMgCl]2[MgCl2(Et2O)2]2

Crystal structure of [tBuMgCl]2[MgCl2(Et2O)2]2

The title compound, di-μ3-chlorido-tetra-μ2-chlorido-tetrakis(diethyl ether-κO)bis(1,1-dimethylethyl)tetramagnesium, [Mg4(C4H9)2Cl6(C4H10O)4], features an Mg4Cl6 open-cube cluster. The two four-coordinate Mg2+ ions show an almost tetrahedral coordination, whereas the two six-coordinate Mg2+ ions hav...

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Bibliographic Details
Main Authors: Maurice Metzler, Michael Bolte, Matthias Wagner, Hans-Wolfram Lerner
Format: Article
Language:English
Published: International Union of Crystallography 2023-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
grignard reagent
open-cube cluster
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023002190

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