Influence of the Substituents on the Opening of Silylepoxy Alcohols: 5-<i>exo</i>-Cyclization towards Tetrahydrofurans vs. Unexpected Side Reaction Leading to Tetrahydropyrans
The regioselective ring opening of epoxy alcohols is an effective method for the synthesis of different types of oxacycles. The 5-<i>exo</i> opening being preferred vs. the 6-<i>endo</i> mode, according to Baldwin rules, the use of silyl-substituted oxiranes has been reported...
Main Authors: | Carlos Díez-Poza, Asunción Barbero |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2021-12-01
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Series: | Molecules |
Subjects: | |
Online Access: | https://www.mdpi.com/1420-3049/26/23/7386 |
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