Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea

While an addition product was formed by the reaction of AZADO (2-azaadamantane N-oxyl) with TCNQF4 (2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane), the reaction of AZADO with thiourea provided an inclusion compound, in which AZADO molecules are incorporated in cylindrical channels formed by t...

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Main Authors: Hideto Suzuki, Yuta Kawahara, Hiroki Akutsu, Jun-ichi Yamada, Shin’ichi Nakatsuji
Format: Article
Language:English
Published: Beilstein-Institut 2013-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.9.169
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author Hideto Suzuki
Yuta Kawahara
Hiroki Akutsu
Jun-ichi Yamada
Shin’ichi Nakatsuji
author_facet Hideto Suzuki
Yuta Kawahara
Hiroki Akutsu
Jun-ichi Yamada
Shin’ichi Nakatsuji
author_sort Hideto Suzuki
collection DOAJ
description While an addition product was formed by the reaction of AZADO (2-azaadamantane N-oxyl) with TCNQF4 (2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane), the reaction of AZADO with thiourea provided an inclusion compound, in which AZADO molecules are incorporated in cylindrical channels formed by thiourea molecules.
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spelling doaj.art-a70ffe399e2d4648a2b0a33f0eb61ed72022-12-21T18:15:13ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-07-01911487149110.3762/bjoc.9.1691860-5397-9-169Structures of the reaction products of the AZADO radical with TCNQF4 or thioureaHideto Suzuki0Yuta Kawahara1Hiroki Akutsu2Jun-ichi Yamada3Shin’ichi Nakatsuji4Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164While an addition product was formed by the reaction of AZADO (2-azaadamantane N-oxyl) with TCNQF4 (2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane), the reaction of AZADO with thiourea provided an inclusion compound, in which AZADO molecules are incorporated in cylindrical channels formed by thiourea molecules.https://doi.org/10.3762/bjoc.9.169adductinclusion compoundnitroxide radicalTCNQF4thiourea
spellingShingle Hideto Suzuki
Yuta Kawahara
Hiroki Akutsu
Jun-ichi Yamada
Shin’ichi Nakatsuji
Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
Beilstein Journal of Organic Chemistry
adduct
inclusion compound
nitroxide radical
TCNQF4
thiourea
title Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
title_full Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
title_fullStr Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
title_full_unstemmed Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
title_short Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea
title_sort structures of the reaction products of the azado radical with tcnqf4 or thiourea
topic adduct
inclusion compound
nitroxide radical
TCNQF4
thiourea
url https://doi.org/10.3762/bjoc.9.169
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