Identification of Mint Scents Using a QCM Based E-Nose

Mints emit diverse scents that exert specific biological functions and are relevance for applications. The current work strives to develop electronic noses that can electronically discriminate the scents emitted by different species of Mint as alternative to conventional profiling by gas chromatogra...

Full description

Bibliographic Details
Main Authors: Salih Okur, Mohammed Sarheed, Robert Huber, Zejun Zhang, Lars Heinke, Adnan Kanbar, Christof Wöll, Peter Nick, Uli Lemmer
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Chemosensors
Subjects:
Online Access:https://www.mdpi.com/2227-9040/9/2/31
_version_ 1797415271923712000
author Salih Okur
Mohammed Sarheed
Robert Huber
Zejun Zhang
Lars Heinke
Adnan Kanbar
Christof Wöll
Peter Nick
Uli Lemmer
author_facet Salih Okur
Mohammed Sarheed
Robert Huber
Zejun Zhang
Lars Heinke
Adnan Kanbar
Christof Wöll
Peter Nick
Uli Lemmer
author_sort Salih Okur
collection DOAJ
description Mints emit diverse scents that exert specific biological functions and are relevance for applications. The current work strives to develop electronic noses that can electronically discriminate the scents emitted by different species of Mint as alternative to conventional profiling by gas chromatography. Here, 12 different sensing materials including 4 different metal oxide nanoparticle dispersions (AZO, ZnO, SnO<sub>2</sub>, ITO), one Metal Organic Frame as Cu(BPDC), and 7 different polymer films, including PVA, PEDOT:PSS, PFO, SB, SW, SG, and PB were used for functionalizing of Quartz Crystal Microbalance (QCM) sensors. The purpose was to discriminate six economically relevant Mint species (<i>Mentha x piperita</i>, <i>Mentha spicata</i>, <i>Mentha spicata ssp. crispa, Mentha longifolia</i>, <i>Agastache rugosa, and Nepeta cataria</i>). The adsorption and desorption datasets obtained from each modified QCM sensor were processed by three different classification models, including Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA), and k-Nearest Neighbor Analysis (k-NN). This allowed discriminating the different Mints with classification accuracies of 97.2% (PCA), 100% (LDA), and 99.9% (k-NN), respectively. Prediction accuracies with a repeating test measurement reached up to 90.6% for LDA, and 85.6% for k-NN. These data demonstrate that this electronic nose can discriminate different Mint scents in a reliable and efficient manner.
first_indexed 2024-03-09T05:46:25Z
format Article
id doaj.art-a7117db289b44db7ae21e42b07c10858
institution Directory Open Access Journal
issn 2227-9040
language English
last_indexed 2024-03-09T05:46:25Z
publishDate 2021-02-01
publisher MDPI AG
record_format Article
series Chemosensors
spelling doaj.art-a7117db289b44db7ae21e42b07c108582023-12-03T12:21:20ZengMDPI AGChemosensors2227-90402021-02-01923110.3390/chemosensors9020031Identification of Mint Scents Using a QCM Based E-NoseSalih Okur0Mohammed Sarheed1Robert Huber2Zejun Zhang3Lars Heinke4Adnan Kanbar5Christof Wöll6Peter Nick7Uli Lemmer8Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Hermann-Von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, 76344 Karlsruhe, GermanyKarlsruhe Institute of Technology, Botanical Institute, Molecular Cell Biology, Fritz-Haber-Weg, 76131 Karlsruhe, GermanyLight Technology Institute, Karlsruhe Institute of Technology, Engesserstraße 13, 76131 Karlsruhe, GermanyInstitute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Hermann-Von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, 76344 Karlsruhe, GermanyLight Technology Institute, Karlsruhe Institute of Technology, Engesserstraße 13, 76131 Karlsruhe, GermanyKarlsruhe Institute of Technology, Botanical Institute, Molecular Cell Biology, Fritz-Haber-Weg, 76131 Karlsruhe, GermanyInstitute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Hermann-Von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, 76344 Karlsruhe, GermanyKarlsruhe Institute of Technology, Botanical Institute, Molecular Cell Biology, Fritz-Haber-Weg, 76131 Karlsruhe, GermanyLight Technology Institute, Karlsruhe Institute of Technology, Engesserstraße 13, 76131 Karlsruhe, GermanyMints emit diverse scents that exert specific biological functions and are relevance for applications. The current work strives to develop electronic noses that can electronically discriminate the scents emitted by different species of Mint as alternative to conventional profiling by gas chromatography. Here, 12 different sensing materials including 4 different metal oxide nanoparticle dispersions (AZO, ZnO, SnO<sub>2</sub>, ITO), one Metal Organic Frame as Cu(BPDC), and 7 different polymer films, including PVA, PEDOT:PSS, PFO, SB, SW, SG, and PB were used for functionalizing of Quartz Crystal Microbalance (QCM) sensors. The purpose was to discriminate six economically relevant Mint species (<i>Mentha x piperita</i>, <i>Mentha spicata</i>, <i>Mentha spicata ssp. crispa, Mentha longifolia</i>, <i>Agastache rugosa, and Nepeta cataria</i>). The adsorption and desorption datasets obtained from each modified QCM sensor were processed by three different classification models, including Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA), and k-Nearest Neighbor Analysis (k-NN). This allowed discriminating the different Mints with classification accuracies of 97.2% (PCA), 100% (LDA), and 99.9% (k-NN), respectively. Prediction accuracies with a repeating test measurement reached up to 90.6% for LDA, and 85.6% for k-NN. These data demonstrate that this electronic nose can discriminate different Mint scents in a reliable and efficient manner.https://www.mdpi.com/2227-9040/9/2/31mintplant volatileselectronic noseprincipal component analysislinear discriminant analysisk-nearest-neighbors analysis
spellingShingle Salih Okur
Mohammed Sarheed
Robert Huber
Zejun Zhang
Lars Heinke
Adnan Kanbar
Christof Wöll
Peter Nick
Uli Lemmer
Identification of Mint Scents Using a QCM Based E-Nose
Chemosensors
mint
plant volatiles
electronic nose
principal component analysis
linear discriminant analysis
k-nearest-neighbors analysis
title Identification of Mint Scents Using a QCM Based E-Nose
title_full Identification of Mint Scents Using a QCM Based E-Nose
title_fullStr Identification of Mint Scents Using a QCM Based E-Nose
title_full_unstemmed Identification of Mint Scents Using a QCM Based E-Nose
title_short Identification of Mint Scents Using a QCM Based E-Nose
title_sort identification of mint scents using a qcm based e nose
topic mint
plant volatiles
electronic nose
principal component analysis
linear discriminant analysis
k-nearest-neighbors analysis
url https://www.mdpi.com/2227-9040/9/2/31
work_keys_str_mv AT salihokur identificationofmintscentsusingaqcmbasedenose
AT mohammedsarheed identificationofmintscentsusingaqcmbasedenose
AT roberthuber identificationofmintscentsusingaqcmbasedenose
AT zejunzhang identificationofmintscentsusingaqcmbasedenose
AT larsheinke identificationofmintscentsusingaqcmbasedenose
AT adnankanbar identificationofmintscentsusingaqcmbasedenose
AT christofwoll identificationofmintscentsusingaqcmbasedenose
AT peternick identificationofmintscentsusingaqcmbasedenose
AT ulilemmer identificationofmintscentsusingaqcmbasedenose