(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium
In the title compound, [Cd(C8H7O3)2(C14H12N2)], the CdII ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenzoate ligand are each...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812010835 |
| _version_ | 1818959753752084480 |
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| author | Heng Zhang Pei-Zheng Zhao |
| author_facet | Heng Zhang Pei-Zheng Zhao |
| author_sort | Heng Zhang |
| collection | DOAJ |
| description | In the title compound, [Cd(C8H7O3)2(C14H12N2)], the CdII ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, molecules are linked by C—H...O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking interactions between the dmphen rings of neighboring molecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å. |
| first_indexed | 2024-12-20T11:46:39Z |
| format | Article |
| id | doaj.art-a712f4b511e049e99509e4bd205ad8fc |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:46:39Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a712f4b511e049e99509e4bd205ad8fc2022-12-21T19:41:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m443m44310.1107/S1600536812010835(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmiumHeng ZhangPei-Zheng ZhaoIn the title compound, [Cd(C8H7O3)2(C14H12N2)], the CdII ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, molecules are linked by C—H...O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking interactions between the dmphen rings of neighboring molecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812010835 |
| spellingShingle | Heng Zhang Pei-Zheng Zhao (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium Acta Crystallographica Section E |
| title | (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium |
| title_full | (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium |
| title_fullStr | (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium |
| title_full_unstemmed | (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium |
| title_short | (2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-methoxybenzoato-κ2O1,O1′)cadmium |
| title_sort | 2 9 dimethyl 1 10 phenanthroline amp 954 2n n amp 8242 bis 2 methoxybenzoato amp 954 2o1 o1 amp 8242 cadmium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812010835 |
| work_keys_str_mv | AT hengzhang 29dimethyl110phenanthrolineamp9542nnamp8242bis2methoxybenzoatoamp9542o1o1amp8242cadmium AT peizhengzhao 29dimethyl110phenanthrolineamp9542nnamp8242bis2methoxybenzoatoamp9542o1o1amp8242cadmium |