Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery
The lithium solvation structure in the electrolyte solution for lithium-ion batteries has not been fully understood. Here, the authors show ultrafast fluxional exchange of carbonate solvent molecules in and out of lithium-ion solvation sheath utilizing coherent two-dimensional infrared spectroscopy.
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2017-03-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms14658 |
| _version_ | 1818845465943212032 |
|---|---|
| author | Kyung-Koo Lee Kwanghee Park Hochan Lee Yohan Noh Dorota Kossowska Kyungwon Kwak Minhaeng Cho |
| author_facet | Kyung-Koo Lee Kwanghee Park Hochan Lee Yohan Noh Dorota Kossowska Kyungwon Kwak Minhaeng Cho |
| author_sort | Kyung-Koo Lee |
| collection | DOAJ |
| description | The lithium solvation structure in the electrolyte solution for lithium-ion batteries has not been fully understood. Here, the authors show ultrafast fluxional exchange of carbonate solvent molecules in and out of lithium-ion solvation sheath utilizing coherent two-dimensional infrared spectroscopy. |
| first_indexed | 2024-12-19T05:30:06Z |
| format | Article |
| id | doaj.art-a72668c7ac424a51ad44add9becd58a6 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T05:30:06Z |
| publishDate | 2017-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-a72668c7ac424a51ad44add9becd58a62022-12-21T20:34:16ZengNature PortfolioNature Communications2041-17232017-03-01811910.1038/ncomms14658Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion batteryKyung-Koo Lee0Kwanghee Park1Hochan Lee2Yohan Noh3Dorota Kossowska4Kyungwon Kwak5Minhaeng Cho6Department of Chemistry, Kunsan National UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityCenter for Molecular Spectroscopy and Dynamics, Institute for Basic Science (IBS), Korea UniversityThe lithium solvation structure in the electrolyte solution for lithium-ion batteries has not been fully understood. Here, the authors show ultrafast fluxional exchange of carbonate solvent molecules in and out of lithium-ion solvation sheath utilizing coherent two-dimensional infrared spectroscopy.https://doi.org/10.1038/ncomms14658 |
| spellingShingle | Kyung-Koo Lee Kwanghee Park Hochan Lee Yohan Noh Dorota Kossowska Kyungwon Kwak Minhaeng Cho Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery Nature Communications |
| title | Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| title_full | Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| title_fullStr | Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| title_full_unstemmed | Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| title_short | Ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| title_sort | ultrafast fluxional exchange dynamics in electrolyte solvation sheath of lithium ion battery |
| url | https://doi.org/10.1038/ncomms14658 |
| work_keys_str_mv | AT kyungkoolee ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT kwangheepark ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT hochanlee ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT yohannoh ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT dorotakossowska ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT kyungwonkwak ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery AT minhaengcho ultrafastfluxionalexchangedynamicsinelectrolytesolvationsheathoflithiumionbattery |