catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data
The asymetric unit of the title compound, [NiCl2(C5H5N)2]n, contains two NiII ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each NiII ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810001820 |
| _version_ | 1819278054147489792 |
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| author | Edith Alig Thomas Bernert Lothar Fink Nevzat Külcü Tuncay Yeşilkaynak |
| author_facet | Edith Alig Thomas Bernert Lothar Fink Nevzat Külcü Tuncay Yeşilkaynak |
| author_sort | Edith Alig |
| collection | DOAJ |
| description | The asymetric unit of the title compound, [NiCl2(C5H5N)2]n, contains two NiII ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each NiII ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) and 11.0 (2)° for the two centers, and four chloride anions in a distorted octahedral geometry. The chloride anions bridge NiII ions related by translation along the short b axes into two crystallographically independent polymeric chains. |
| first_indexed | 2024-12-24T00:05:54Z |
| format | Article |
| id | doaj.art-a735bb748e0f4918860bf6b71d36ce7a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:05:54Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a735bb748e0f4918860bf6b71d36ce7a2022-12-21T17:25:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m239m23910.1107/S1600536810001820catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder dataEdith AligThomas BernertLothar FinkNevzat KülcüTuncay YeşilkaynakThe asymetric unit of the title compound, [NiCl2(C5H5N)2]n, contains two NiII ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each NiII ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) and 11.0 (2)° for the two centers, and four chloride anions in a distorted octahedral geometry. The chloride anions bridge NiII ions related by translation along the short b axes into two crystallographically independent polymeric chains.http://scripts.iucr.org/cgi-bin/paper?S1600536810001820 |
| spellingShingle | Edith Alig Thomas Bernert Lothar Fink Nevzat Külcü Tuncay Yeşilkaynak catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data Acta Crystallographica Section E |
| title | catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data |
| title_full | catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data |
| title_fullStr | catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data |
| title_full_unstemmed | catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data |
| title_short | catena-Poly[[dipyridinenickel(II)]-trans-di-μ-chlorido] from powder data |
| title_sort | catena poly dipyridinenickel ii trans di amp 956 chlorido from powder data |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810001820 |
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