Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia

Chagan Sag is one of the most significant tectonic unit in the Yin'e Basin. The special component of the organic macerals and biomarkers in the Chagan sag suggests great difference of its hydrocarbon generation process. In this paper, forty samples of source rocks are subjected to carry out on...

Full description

Bibliographic Details
Main Authors: Wenjie Xiao, Hong Ji, Guanghui Huang
Format: Article
Language:English
Published: Elsevier 2023-03-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023011805
_version_ 1797851930373914624
author Wenjie Xiao
Hong Ji
Guanghui Huang
author_facet Wenjie Xiao
Hong Ji
Guanghui Huang
author_sort Wenjie Xiao
collection DOAJ
description Chagan Sag is one of the most significant tectonic unit in the Yin'e Basin. The special component of the organic macerals and biomarkers in the Chagan sag suggests great difference of its hydrocarbon generation process. In this paper, forty samples of source rocks are subjected to carry out on the geochemical characteristics by methods of rock-eval analysis, organic petrology and gas chromatography mass spectrometry (GC-MS) to reveal the origin, depositional environment and maturity of organic matter in Chagan Sag, Yin'e Basin of Inner Mongolia. The total organic matter of the analyzed samples ranges from 0.4 wt%∼3.89 wt% with an average of 1.12 wt%, indicating fair to excellent hydrocarbon generation potential. The rock-eval results show that the S1+S2 and hydrocarbon index range from 0.03 mg/g∼16.34 mg/g (avg.3.6 mg/g) and 6.24–521.32 mg/g (avg. 199.63 mg/g), suggesting most of the kerogen types are type II and III, with small amount of type I. The Tmax ranges from 428 to 496 °C, suggesting low mature to mature stage. The macerals component of morphological macerals presents with certain amount of vitrinite, liptinite and some inertinite. However, the amorphous component takes the dominant part of the macerals with account of 50%–80%. The amorphous components are dominated by sapropelite in the source rock, indicating bacteriolytic amorphous promote the organic generation process. Hopanes and sterane are widely distributed in the source rocks. The biomarker results suggest a mix of planktonic-bacterial and higher plant origins, with wide range of thermal maturity and relatively reducing depositional environment. Abnormal high content of hopanes were observed in the biomarkers, and some special biomarkers such as monomethylalkanes, long-chain-alkyl naphthalenes, aromatized de A-triterpenes, 8,14-seco-triterpenes, and A, B-cyclostane are detected in Chagan Sag. The presence of these compounds suggests that bacterial and microorganisms are of great significance to the generation of hydrocarbon in the source rock in Chagan Sag.
first_indexed 2024-04-09T19:24:46Z
format Article
id doaj.art-a73c8cd9a8b04a80b83f5ce4f9d958fe
institution Directory Open Access Journal
issn 2405-8440
language English
last_indexed 2024-04-09T19:24:46Z
publishDate 2023-03-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj.art-a73c8cd9a8b04a80b83f5ce4f9d958fe2023-04-05T08:20:07ZengElsevierHeliyon2405-84402023-03-0193e13973Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner MongoliaWenjie Xiao0Hong Ji1Guanghui Huang2College of Science, Guangdong University of Petrochemical Technology, Maoming Guangdong 525000, China; College of Resources and Environment, Yangtze University, Wuhan 430100, Hubei, ChinaCollege of Science, Guangdong University of Petrochemical Technology, Maoming Guangdong 525000, China; Corresponding author.College of Resources and Environment, Yangtze University, Wuhan 430100, Hubei, China; Corresponding author.Chagan Sag is one of the most significant tectonic unit in the Yin'e Basin. The special component of the organic macerals and biomarkers in the Chagan sag suggests great difference of its hydrocarbon generation process. In this paper, forty samples of source rocks are subjected to carry out on the geochemical characteristics by methods of rock-eval analysis, organic petrology and gas chromatography mass spectrometry (GC-MS) to reveal the origin, depositional environment and maturity of organic matter in Chagan Sag, Yin'e Basin of Inner Mongolia. The total organic matter of the analyzed samples ranges from 0.4 wt%∼3.89 wt% with an average of 1.12 wt%, indicating fair to excellent hydrocarbon generation potential. The rock-eval results show that the S1+S2 and hydrocarbon index range from 0.03 mg/g∼16.34 mg/g (avg.3.6 mg/g) and 6.24–521.32 mg/g (avg. 199.63 mg/g), suggesting most of the kerogen types are type II and III, with small amount of type I. The Tmax ranges from 428 to 496 °C, suggesting low mature to mature stage. The macerals component of morphological macerals presents with certain amount of vitrinite, liptinite and some inertinite. However, the amorphous component takes the dominant part of the macerals with account of 50%–80%. The amorphous components are dominated by sapropelite in the source rock, indicating bacteriolytic amorphous promote the organic generation process. Hopanes and sterane are widely distributed in the source rocks. The biomarker results suggest a mix of planktonic-bacterial and higher plant origins, with wide range of thermal maturity and relatively reducing depositional environment. Abnormal high content of hopanes were observed in the biomarkers, and some special biomarkers such as monomethylalkanes, long-chain-alkyl naphthalenes, aromatized de A-triterpenes, 8,14-seco-triterpenes, and A, B-cyclostane are detected in Chagan Sag. The presence of these compounds suggests that bacterial and microorganisms are of great significance to the generation of hydrocarbon in the source rock in Chagan Sag.http://www.sciencedirect.com/science/article/pii/S2405844023011805Microbial effectOrganic matterSource rockInner Mongolia
spellingShingle Wenjie Xiao
Hong Ji
Guanghui Huang
Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
Heliyon
Microbial effect
Organic matter
Source rock
Inner Mongolia
title Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
title_full Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
title_fullStr Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
title_full_unstemmed Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
title_short Geochemical characteristics and implications of hydrocarbon in source rocks of Chagan Sag, Yin'e basin of Inner Mongolia
title_sort geochemical characteristics and implications of hydrocarbon in source rocks of chagan sag yin e basin of inner mongolia
topic Microbial effect
Organic matter
Source rock
Inner Mongolia
url http://www.sciencedirect.com/science/article/pii/S2405844023011805
work_keys_str_mv AT wenjiexiao geochemicalcharacteristicsandimplicationsofhydrocarboninsourcerocksofchagansagyinebasinofinnermongolia
AT hongji geochemicalcharacteristicsandimplicationsofhydrocarboninsourcerocksofchagansagyinebasinofinnermongolia
AT guanghuihuang geochemicalcharacteristicsandimplicationsofhydrocarboninsourcerocksofchagansagyinebasinofinnermongolia